用收缩核模型研究不变尺寸平板颗粒气固反应的转化

Q4 Chemical Engineering
Ehsan Zangooei, M. R. Talaghat
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引用次数: 0

摘要

本文采用收缩堆芯模型,建立了平板颗粒流化反应器内塞流和混合流转化反应和停留时间反应的数学模型。在这个模型中,颗粒的大小在反应过程中是不变的。反应速率受气层阻力、灰层阻力和反应阻力及其组合的控制。还假设气体从侧面扩散,而忽略轴向扩散的影响。方程用数值方法求解。本文的创新之处在于研究了各种阻力对反应转化的影响。特定时间的结果表明,当反应速率由各电阻单独控制时,转化率较大。例如,当反应由灰层电阻控制时,与其他两种电阻控制时。最后,研究了不同控制机制的组合对颗粒塞流和混合流的转化和反应停留时间的影响,发现总体结果相似。此外,所得的气膜层电阻曲线与化学反应电阻曲线是一致且相互对应的。因为转化率的方程是一样的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Conversion of Gas-Solid Reactions of the Flat Plate Particles with Unchanged Size Using the Shrinking Core Model
In this paper, a mathematical model is developed to calculate the conversion and the residence time reaction for plug flow and mixed flow in the fluidized reactors filled with flat plate particles using the shrinking core model. In this modeling, the size of the particles is unchanged during the reaction. Also, the reaction rate is controlled by the gas layer resistance, the ash layer resistance, and the reaction resistance as well as the combination of them. It is also assumed that the gas diffuses from the side, whereas the effect of diffusion in the axial direction is neglected. Equations are solved by numerical methods. This paper's innovation is investigating the combination of resistances effect on the conversion of the reaction. The results for a specific time show that when the reaction rate is controlled by each of the resistances individually, the conversion rate is greater. For example when the reaction is controlled by the ash layer resistance versus when the other two resistance regimes control it. Finally, the effect of the combination of different controlling regimes on the conversion and residence time of reaction for plug flow and mixed flow of particles is studied and it is found that the overall results are similar to each other. In addition, the results that the curves for the gas film layer resistance and the chemical reaction resistance, are the same and correspond to each other. Because the equations of the conversion rate are the same.
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CiteScore
1.20
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