{"title":"弹性土乙醇提取物在0.5 M H2SO4中对低碳钢的缓蚀作用","authors":"C. B. Adindu, Emeka Emanuel Oguzie, C. Ogukwe","doi":"10.18052/WWW.SCIPRESS.COM/ILCPA.68.24","DOIUrl":null,"url":null,"abstract":"The adsorption and corrosion inhibitive effect of the ethanol extract of Funtumia elastica (FE) leaves on mild steel corrosion in 0.5 M H2SO4 was studied using gravimetric, potentiodynamic polarization and electrochemical impedance spectroscopic techniques. As well as Fourier transform infrared spectroscopy and computational methods. The gravimetric and electrochemical studies revealed that FE is an adsorption inhibitor. The potentiodynamic polarization result showed that the inhibitor is a mixed type corrosion inhibitor for mild steel in 0.5 M H2SO4, inhibiting both the cathodic and anodic partial reactions. Density functional theory calculations were performed to model the electronic structures of some selected extract constituents (conessine, and ascorbic acid) to confirm their inhibiting potential and established their individual contributions to the observed inhibiting effects.","PeriodicalId":14453,"journal":{"name":"International Letters of Chemistry, Physics and Astronomy","volume":"109 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2016-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Corrosion Inhibition of Mild Steel in 0.5 M H2SO4 Using Ethanol Extract of Funtumia elastica\",\"authors\":\"C. B. Adindu, Emeka Emanuel Oguzie, C. Ogukwe\",\"doi\":\"10.18052/WWW.SCIPRESS.COM/ILCPA.68.24\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The adsorption and corrosion inhibitive effect of the ethanol extract of Funtumia elastica (FE) leaves on mild steel corrosion in 0.5 M H2SO4 was studied using gravimetric, potentiodynamic polarization and electrochemical impedance spectroscopic techniques. As well as Fourier transform infrared spectroscopy and computational methods. The gravimetric and electrochemical studies revealed that FE is an adsorption inhibitor. The potentiodynamic polarization result showed that the inhibitor is a mixed type corrosion inhibitor for mild steel in 0.5 M H2SO4, inhibiting both the cathodic and anodic partial reactions. Density functional theory calculations were performed to model the electronic structures of some selected extract constituents (conessine, and ascorbic acid) to confirm their inhibiting potential and established their individual contributions to the observed inhibiting effects.\",\"PeriodicalId\":14453,\"journal\":{\"name\":\"International Letters of Chemistry, Physics and Astronomy\",\"volume\":\"109 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Letters of Chemistry, Physics and Astronomy\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.18052/WWW.SCIPRESS.COM/ILCPA.68.24\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Letters of Chemistry, Physics and Astronomy","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.18052/WWW.SCIPRESS.COM/ILCPA.68.24","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
摘要
采用重量法、动电位极化法和电化学阻抗谱法研究了弹性土叶乙醇提取物对0.5 M H2SO4中低碳钢腐蚀的吸附和缓蚀作用。以及红外光谱的傅里叶变换和计算方法。重量和电化学研究表明,FE是一种吸附抑制剂。动电位极化结果表明,该缓蚀剂在0.5 M H2SO4中为混合型缓蚀剂,对低碳钢的阴极和阳极部分反应均有抑制作用。通过密度泛函理论计算,对一些选定的提取物成分(conessine和抗坏血酸)的电子结构进行建模,以确定它们的抑制潜力,并确定它们对所观察到的抑制效果的单独贡献。
Corrosion Inhibition of Mild Steel in 0.5 M H2SO4 Using Ethanol Extract of Funtumia elastica
The adsorption and corrosion inhibitive effect of the ethanol extract of Funtumia elastica (FE) leaves on mild steel corrosion in 0.5 M H2SO4 was studied using gravimetric, potentiodynamic polarization and electrochemical impedance spectroscopic techniques. As well as Fourier transform infrared spectroscopy and computational methods. The gravimetric and electrochemical studies revealed that FE is an adsorption inhibitor. The potentiodynamic polarization result showed that the inhibitor is a mixed type corrosion inhibitor for mild steel in 0.5 M H2SO4, inhibiting both the cathodic and anodic partial reactions. Density functional theory calculations were performed to model the electronic structures of some selected extract constituents (conessine, and ascorbic acid) to confirm their inhibiting potential and established their individual contributions to the observed inhibiting effects.