浙江卡兹干选矿厂生产电解铜尾矿浸出液采用水力脉冲排放

Ye.S. Mustafin, K. Omarov, A. Borsynbaev, D. Havlichek, A. Pudov, N.V. Shuyev
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引用次数: 0

摘要

本文首次对浙浙卡干选矿厂尾矿浸出前后的矿物学组成和化学半定量光谱分析(SQSA)进行了研究。结果表明,铜在尾矿中以硫铜矿物和硼铁矿物的形式存在。在使用氟化二铵和水脉冲放电浸出后,硫胺和硼铁矿被破坏,铜进入含有磷酸的溶液中。由于多次将尾矿放入溶液中,其中的铜含量达到可以在不锈钢板上沉积铜的浓度。采用LAES-Matrix颗粒谱仪对铜进行了鉴定。使用TESCAN MIRA扫描电子显微镜对处理后的矿石废物结构变化进行了视觉比较分析。在实验装置中,通过电化学反应从溶液中得到金属铜。该技术是在金属铜的萃取实验装置上开发的,从溶液介质的选择和电化学过程的选择到获得纯度为99.99%的目标金属的阶段
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Production of electrolytic copper from Zhezkazgan Processing Plant tailings leaching solutions using a hydro-impulse discharge
In this work, for the first time, studies of the mineralogical composition and chemical semi-quantitative spectral analysis (SQSA) of the Zhezkazgan processing plant tailings before and after leaching were carried out. It was found that copper is present in the tailings in the form of the chalcosine and bornite minerals. After leaching with the use of ammonium bifluoride and a hydro-pulse discharge, chalcosine and boronite are destroyed, and copper passes into a solution containing phosphoric acid. As a result of multiple placing of tailings into the solution, the copper content in it is brought to a concentration at which copper deposition on a stainless steel plate is possible. The identification of copper was implemented on a LAES-Matrix grain spectrometer. A visual comparative analysis of the changes in the structure of the treated ore waste was carried out using a TESCAN MIRA scanning electron microscope. Metallic copper was obtained from solution by electrochemical reactions in an experimental laboratory setup as a result. The technology was developed on an experimental laboratory setup for the extraction of metallic copper and brought the choice of the solution medium and electrochemical processes to the stage of obtaining the target metal with a purity of 99.99 %
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