{"title":"Salen钴(III)叠氮配合物Na[Co(Salen)(N3)2]的晶体结构","authors":"M. Weil, A. D. Khalaji","doi":"10.2116/ANALSCIX.24.X19","DOIUrl":null,"url":null,"abstract":"The cobalt(III) azido complex, Na[Co(salen)(N3)2], contains a Co(III) cation in a distorted octahedral coordination. The equatorial plane of the octahedron is defined by two N and two O atoms from the tetradentate salen ligand, and the axial ligands belong to two terminal N atoms from two different azide anions. Via interactions between the Na+ cations and the N and O atoms of the ligands, the [Co(salen)(N3)2]- anions are connected into a polymeric structure, forming corrugated ribbons parallel to [100].","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"15 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"Crystal Structure of the Salen Cobalt(III) Azido Complex Na[Co(salen)(N3)2]\",\"authors\":\"M. Weil, A. D. Khalaji\",\"doi\":\"10.2116/ANALSCIX.24.X19\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The cobalt(III) azido complex, Na[Co(salen)(N3)2], contains a Co(III) cation in a distorted octahedral coordination. The equatorial plane of the octahedron is defined by two N and two O atoms from the tetradentate salen ligand, and the axial ligands belong to two terminal N atoms from two different azide anions. Via interactions between the Na+ cations and the N and O atoms of the ligands, the [Co(salen)(N3)2]- anions are connected into a polymeric structure, forming corrugated ribbons parallel to [100].\",\"PeriodicalId\":7796,\"journal\":{\"name\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"volume\":\"15 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2008-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2116/ANALSCIX.24.X19\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X19","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Crystal Structure of the Salen Cobalt(III) Azido Complex Na[Co(salen)(N3)2]
The cobalt(III) azido complex, Na[Co(salen)(N3)2], contains a Co(III) cation in a distorted octahedral coordination. The equatorial plane of the octahedron is defined by two N and two O atoms from the tetradentate salen ligand, and the axial ligands belong to two terminal N atoms from two different azide anions. Via interactions between the Na+ cations and the N and O atoms of the ligands, the [Co(salen)(N3)2]- anions are connected into a polymeric structure, forming corrugated ribbons parallel to [100].
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