三(三甲基硅烷基)硅烷

Encyclopedia of Reagents for Organic Synthesis Pub Date : 2003-04-28 DOI:10.1002/9780470842898.RT420.PUB2

B. Giese, J. Dickhaut, C. Chatgilialoglu

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引用次数: 1

摘要

[1873-77-4] C9H28Si4 (MW 248.73) InChI = 1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1- 9h3 InChIKey = SQMFULTZZQBFBM-UHFFFAOYSA-N(自由基反应介质)替代名称:TTmss(Tms)3SiH物理数据:bp 82-84°C/12 mmHg;D 0.806 g cm−3;n20D 1.489。溶解度:溶胶戊烷、醚、甲苯、四氢呋喃;适度溶胶丙酮、乙腈;insol水;在甲醇和其它醇中迅速分解。供应形式:无色液体;商业上可用。3 .制备方法:制备简便处理、储存及注意事项:对氧气略敏感，应在氮气下储存在几种生物试验系统中均无毒性

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Tris(trimethylsilyl)silane

[1873-77-4] C9H28Si4 (MW 248.73) InChI = 1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3 InChIKey = SQMFULTZZQBFBM-UHFFFAOYSA-N (mediator of radical reactions;1, 2 nontoxic substitute for tri-n-butylstannane in radical reactions; slower hydrogen donor than tri-n-butylstannane3) Alternatives names: TTmss(Tms)3SiH Physical Data: bp 82–84 °C/12 mmHg; d 0.806 g cm−3; n20D 1.489. Solubility: sol pentane, ether, toluene, THF; modestly sol acetone, acetonitrile; insol H2O; decomposes rapidly in methanol and other alcohols. Form Supplied in: colorless liquid; commercially available. Preparative Method: easy to synthesize.4 Handling, Storage, and Precautions: is slightly sensitive to oxygen and should be stored under nitrogen.5 It showed no toxicity in several biological test systems.6

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Encyclopedia of Reagents for Organic Synthesis

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