{"title":"二氧化硒氧化苯并氢和Þ-Chlorobenzhydrol的研究:反应动力学","authors":"D. Dwivedi, A. Dwivedi, N. Manikpuri","doi":"10.20431/2349-0403.0602001","DOIUrl":null,"url":null,"abstract":"It is known from a long time that rare earths compound viz. Selenium dioxide (SeO2), Selenious and Selenic acids as well as selenites are readily reduced by a variety of substances to selenium but their oxidizing properties were not studies systematically. Riley, Morley and Friend 1 were the first pioneer to introduce the potential of SeO2 as an oxidant, since then considerable progress has been made for the oxidation of a large number of organic compounds. 2 In presence of strong mineral acids such as H2SO4, it gives rise existing active oxidizing species H3SeO3 + or AcH3SeO3 to cause the reaction.","PeriodicalId":13721,"journal":{"name":"International Journal of Advanced Research in Chemical Science","volume":"148 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on Oxidation of Benzhydrol and Þ-Chlorobenzhydrol by Selenium Dioxide: Reaction Kinetics\",\"authors\":\"D. Dwivedi, A. Dwivedi, N. Manikpuri\",\"doi\":\"10.20431/2349-0403.0602001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"It is known from a long time that rare earths compound viz. Selenium dioxide (SeO2), Selenious and Selenic acids as well as selenites are readily reduced by a variety of substances to selenium but their oxidizing properties were not studies systematically. Riley, Morley and Friend 1 were the first pioneer to introduce the potential of SeO2 as an oxidant, since then considerable progress has been made for the oxidation of a large number of organic compounds. 2 In presence of strong mineral acids such as H2SO4, it gives rise existing active oxidizing species H3SeO3 + or AcH3SeO3 to cause the reaction.\",\"PeriodicalId\":13721,\"journal\":{\"name\":\"International Journal of Advanced Research in Chemical Science\",\"volume\":\"148 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Advanced Research in Chemical Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.20431/2349-0403.0602001\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Advanced Research in Chemical Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.20431/2349-0403.0602001","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Study on Oxidation of Benzhydrol and Þ-Chlorobenzhydrol by Selenium Dioxide: Reaction Kinetics
It is known from a long time that rare earths compound viz. Selenium dioxide (SeO2), Selenious and Selenic acids as well as selenites are readily reduced by a variety of substances to selenium but their oxidizing properties were not studies systematically. Riley, Morley and Friend 1 were the first pioneer to introduce the potential of SeO2 as an oxidant, since then considerable progress has been made for the oxidation of a large number of organic compounds. 2 In presence of strong mineral acids such as H2SO4, it gives rise existing active oxidizing species H3SeO3 + or AcH3SeO3 to cause the reaction.
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