Supratim Basak, Ajay Kumar Botcha, M. Ansari, Rajadurai Chandrasekar
{"title":"包覆可可逆切换铁(II)自旋跃迁纳米粒子的光波导有机纳米棒","authors":"Supratim Basak, Ajay Kumar Botcha, M. Ansari, Rajadurai Chandrasekar","doi":"10.1155/2013/136178","DOIUrl":null,"url":null,"abstract":"A dual functional nanohybrid object combining photonic and magnetic properties was successfully prepared through a “bottom-up” self-assembly approach. In this method, spin transition Fe(II) coordination nanoparticles and optical wave guiding organic nanorods were generated in situ and successfully integrated together in a single pot through self-assembly. The Fe(II) nanoparticles coated on organic nanorods (nanohybrids) display temperature dependent reversible spin transition (Paramagnetic; diamagnetic; ) behavior. The nano-hybrids show efficient optical wave guiding behavior, which demonstrates the future possibility to perform light induced excited spin state trapping (LIESST) experiments on a single spin transition nanoparticle level. These photonic and magnetic “nanohybrids” offer promising option to externally manipulate spin state of the spin transition nanoparticles using temperature as well as remote laser light.","PeriodicalId":13278,"journal":{"name":"Indian Journal of Materials Science","volume":"36 1","pages":"1-7"},"PeriodicalIF":0.0000,"publicationDate":"2013-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Optical Waveguiding Organic Nanorods Coated with Reversibly Switchable Fe(II) Spin Transition Nanoparticles\",\"authors\":\"Supratim Basak, Ajay Kumar Botcha, M. Ansari, Rajadurai Chandrasekar\",\"doi\":\"10.1155/2013/136178\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A dual functional nanohybrid object combining photonic and magnetic properties was successfully prepared through a “bottom-up” self-assembly approach. In this method, spin transition Fe(II) coordination nanoparticles and optical wave guiding organic nanorods were generated in situ and successfully integrated together in a single pot through self-assembly. The Fe(II) nanoparticles coated on organic nanorods (nanohybrids) display temperature dependent reversible spin transition (Paramagnetic; diamagnetic; ) behavior. The nano-hybrids show efficient optical wave guiding behavior, which demonstrates the future possibility to perform light induced excited spin state trapping (LIESST) experiments on a single spin transition nanoparticle level. These photonic and magnetic “nanohybrids” offer promising option to externally manipulate spin state of the spin transition nanoparticles using temperature as well as remote laser light.\",\"PeriodicalId\":13278,\"journal\":{\"name\":\"Indian Journal of Materials Science\",\"volume\":\"36 1\",\"pages\":\"1-7\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2013-11-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Indian Journal of Materials Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/2013/136178\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Indian Journal of Materials Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2013/136178","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A dual functional nanohybrid object combining photonic and magnetic properties was successfully prepared through a “bottom-up” self-assembly approach. In this method, spin transition Fe(II) coordination nanoparticles and optical wave guiding organic nanorods were generated in situ and successfully integrated together in a single pot through self-assembly. The Fe(II) nanoparticles coated on organic nanorods (nanohybrids) display temperature dependent reversible spin transition (Paramagnetic; diamagnetic; ) behavior. The nano-hybrids show efficient optical wave guiding behavior, which demonstrates the future possibility to perform light induced excited spin state trapping (LIESST) experiments on a single spin transition nanoparticle level. These photonic and magnetic “nanohybrids” offer promising option to externally manipulate spin state of the spin transition nanoparticles using temperature as well as remote laser light.