羰基催化氧吲哚的区域选择性加成以快速获得烯

IF 1.7 4区化学 Q3 CHEMISTRY, ORGANIC

Synlett Pub Date : 2023-03-16 DOI:10.1055/s-0042-1752718

Cuiyun Sun, Yingling Nong, Chen Pang, Shenmin Zhang, Ting-Peng Li

引用次数: 0

摘要

研究了氧吲哚与ynals的催化区域选择性加成反应。含有各种取代基和取代模式的含烯衍生物通常具有中等至良好的产率和中等的非对映选择性。从该工艺中获得的几种烯在开发新型植物保护杀菌剂中具有重要价值。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Carbene-Catalyzed Regioselective Addition of Oxindoles to Ynals for Quick Access to Allenes

A catalytic regioselective addition reaction of oxindoles with ynals is developed. Allene-containing derivatives bearing various substituents and substitution patterns are afforded as the products in generally moderate to good yields with moderate diastereoselectivities. Several of allenes obtained from this protocol are valuable in the development of novel bactericides for plant protection.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Synlett 化学-有机化学

CiteScore

3.40

自引率

5.00%

发文量

369

审稿时长

1 months

期刊介绍： SYNLETT is an international journal reporting research results and current trends in chemical synthesis in short personalized reviews and preliminary communications. It covers all fields of scientific endeavor that involve organic synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines and offers the possibility to publish scientific primary data.