{"title":"BC2.5N异质金刚石在冲击压缩下的沉积机理","authors":"T. Komatsu, M. Nomura, Y. Kakudate, S. Fujiwara","doi":"10.1039/A800461G","DOIUrl":null,"url":null,"abstract":"Transmission electron microscopy of shock compacted hexagonal BC2.5N indicated the coexistence of morphologically and compositionally complex materials, a large proportion of cubic BC2.5N (heterodiamond), trace amounts of amorphous heterodiamond, atomic-rearranged cubic BC2.5N, an amorphous diamond-like material and onion-like heterofullerene. Such diversities of the products suggested liquid phase-to-solid phase deposition that is affected by the local heterogeneity in the cooling medium surrounding the liquid phase. The possibility of this mechanism was also suggested by kinetic estimations of the shock-compression process.","PeriodicalId":17286,"journal":{"name":"Journal of the Chemical Society, Faraday Transactions","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1998-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"Deposition mechanism of BC2.5N heterodiamond under shock compression\",\"authors\":\"T. Komatsu, M. Nomura, Y. Kakudate, S. Fujiwara\",\"doi\":\"10.1039/A800461G\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Transmission electron microscopy of shock compacted hexagonal BC2.5N indicated the coexistence of morphologically and compositionally complex materials, a large proportion of cubic BC2.5N (heterodiamond), trace amounts of amorphous heterodiamond, atomic-rearranged cubic BC2.5N, an amorphous diamond-like material and onion-like heterofullerene. Such diversities of the products suggested liquid phase-to-solid phase deposition that is affected by the local heterogeneity in the cooling medium surrounding the liquid phase. The possibility of this mechanism was also suggested by kinetic estimations of the shock-compression process.\",\"PeriodicalId\":17286,\"journal\":{\"name\":\"Journal of the Chemical Society, Faraday Transactions\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1998-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Chemical Society, Faraday Transactions\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/A800461G\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Chemical Society, Faraday Transactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/A800461G","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Deposition mechanism of BC2.5N heterodiamond under shock compression
Transmission electron microscopy of shock compacted hexagonal BC2.5N indicated the coexistence of morphologically and compositionally complex materials, a large proportion of cubic BC2.5N (heterodiamond), trace amounts of amorphous heterodiamond, atomic-rearranged cubic BC2.5N, an amorphous diamond-like material and onion-like heterofullerene. Such diversities of the products suggested liquid phase-to-solid phase deposition that is affected by the local heterogeneity in the cooling medium surrounding the liquid phase. The possibility of this mechanism was also suggested by kinetic estimations of the shock-compression process.