使用具有超疏水表面的浓缩装置分析实际样品中的重金属离子

TRANSDUCERS 2007 - 2007 International Solid-State Sensors, Actuators and Microsystems Conference Pub Date : 2007-09-24 DOI:10.1109/SENSOR.2007.4300411

I. Yanagimachi, N. Nashida, K. Iwasa, H. Suzuki

{"title":"使用具有超疏水表面的浓缩装置分析实际样品中的重金属离子","authors":"I. Yanagimachi, N. Nashida, K. Iwasa, H. Suzuki","doi":"10.1109/SENSOR.2007.4300411","DOIUrl":null,"url":null,"abstract":"Heavy metal ions in soil samples were analyzed by a novel method based on evaporative concentration. The detector chip had a microelectrode array as a working electrode and a Ag/AgCl reference electrode surrounded by a super-hydrophobic layer formed with polytetrafluoroethylene (PTFE) beads. A sample droplet formed on the electrode area was shrunk to concentrate the solution. Cd2+ , Pb2+ , and As3+ ions were analyzed by square wave anodic stripping voltammetry. By combining a protective layer and wet sample digestion, the heavy metal ions in soil samples could be analyzed. Correlation coefficients between the values obtained by this method and those by a conventional method was 0.982 (Pb2+), 0.969 (Cd2+), and 0.936 (As3+).","PeriodicalId":23295,"journal":{"name":"TRANSDUCERS 2007 - 2007 International Solid-State Sensors, Actuators and Microsystems Conference","volume":"19 1","pages":"1425-1428"},"PeriodicalIF":0.0000,"publicationDate":"2007-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Analysis of Heavy Metal Ions in Real Samples using a Concentrator Device with a Super-Hydrophobic Surface\",\"authors\":\"I. Yanagimachi, N. Nashida, K. Iwasa, H. Suzuki\",\"doi\":\"10.1109/SENSOR.2007.4300411\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Heavy metal ions in soil samples were analyzed by a novel method based on evaporative concentration. The detector chip had a microelectrode array as a working electrode and a Ag/AgCl reference electrode surrounded by a super-hydrophobic layer formed with polytetrafluoroethylene (PTFE) beads. A sample droplet formed on the electrode area was shrunk to concentrate the solution. Cd2+ , Pb2+ , and As3+ ions were analyzed by square wave anodic stripping voltammetry. By combining a protective layer and wet sample digestion, the heavy metal ions in soil samples could be analyzed. Correlation coefficients between the values obtained by this method and those by a conventional method was 0.982 (Pb2+), 0.969 (Cd2+), and 0.936 (As3+).\",\"PeriodicalId\":23295,\"journal\":{\"name\":\"TRANSDUCERS 2007 - 2007 International Solid-State Sensors, Actuators and Microsystems Conference\",\"volume\":\"19 1\",\"pages\":\"1425-1428\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2007-09-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"TRANSDUCERS 2007 - 2007 International Solid-State Sensors, Actuators and Microsystems Conference\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/SENSOR.2007.4300411\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"TRANSDUCERS 2007 - 2007 International Solid-State Sensors, Actuators and Microsystems Conference","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/SENSOR.2007.4300411","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

采用蒸发浓度法对土壤样品中的重金属离子进行了分析。该检测芯片采用微电极阵列作为工作电极，Ag/AgCl参比电极被聚四氟乙烯(PTFE)微珠形成的超疏水层包裹。在电极区域形成的样品液滴被缩小以浓缩溶液。采用方波阳极溶出伏安法分析Cd2+、Pb2+和As3+离子。采用保护层与湿消解相结合的方法，可以对土壤样品中的重金属离子进行分析。与常规方法的相关系数分别为0.982 (Pb2+)、0.969 (Cd2+)和0.936 (As3+)。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Analysis of Heavy Metal Ions in Real Samples using a Concentrator Device with a Super-Hydrophobic Surface

Heavy metal ions in soil samples were analyzed by a novel method based on evaporative concentration. The detector chip had a microelectrode array as a working electrode and a Ag/AgCl reference electrode surrounded by a super-hydrophobic layer formed with polytetrafluoroethylene (PTFE) beads. A sample droplet formed on the electrode area was shrunk to concentrate the solution. Cd2+ , Pb2+ , and As3+ ions were analyzed by square wave anodic stripping voltammetry. By combining a protective layer and wet sample digestion, the heavy metal ions in soil samples could be analyzed. Correlation coefficients between the values obtained by this method and those by a conventional method was 0.982 (Pb2+), 0.969 (Cd2+), and 0.936 (As3+).

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

TRANSDUCERS 2007 - 2007 International Solid-State Sensors, Actuators and Microsystems Conference

自引率

0.00%

发文量