{"title":"羧酸宿主与醇客体超分子配合物中相互作用模式的平衡。MeOH和EtOH包合物的x射线晶体结构","authors":"Ingeborg Csöregh , Edwin Weber , Stefan Finge","doi":"10.1016/S1463-0184(02)00005-9","DOIUrl":null,"url":null,"abstract":"<div><p>Remarkable differences have been observed between the host–guest interaction modes in two closely related crystalline inclusion compounds [<strong>1</strong>·MeOH (1:1) and <strong>1</strong>·EtOH(1:1)] of the same carboxylic host (<strong>1</strong>). The minor modification of the guest structure crucially affected the hydrogen bonding recognition pattern between given complementary groups, which demonstrates the sensitive balance of intermolecular interaction modes that must be controlled for successful crystal engineering and design of supramolecular compounds.</p></div>","PeriodicalId":10766,"journal":{"name":"Crystal Engineering","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2002-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1463-0184(02)00005-9","citationCount":"5","resultStr":"{\"title\":\"On the balance of interaction modes in supramolecular complexes of a carboxylic acid host and alcohol guests. X-ray crystal structures of inclusion compounds with MeOH and EtOH\",\"authors\":\"Ingeborg Csöregh , Edwin Weber , Stefan Finge\",\"doi\":\"10.1016/S1463-0184(02)00005-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Remarkable differences have been observed between the host–guest interaction modes in two closely related crystalline inclusion compounds [<strong>1</strong>·MeOH (1:1) and <strong>1</strong>·EtOH(1:1)] of the same carboxylic host (<strong>1</strong>). The minor modification of the guest structure crucially affected the hydrogen bonding recognition pattern between given complementary groups, which demonstrates the sensitive balance of intermolecular interaction modes that must be controlled for successful crystal engineering and design of supramolecular compounds.</p></div>\",\"PeriodicalId\":10766,\"journal\":{\"name\":\"Crystal Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1463-0184(02)00005-9\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Crystal Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1463018402000059\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1463018402000059","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
On the balance of interaction modes in supramolecular complexes of a carboxylic acid host and alcohol guests. X-ray crystal structures of inclusion compounds with MeOH and EtOH
Remarkable differences have been observed between the host–guest interaction modes in two closely related crystalline inclusion compounds [1·MeOH (1:1) and 1·EtOH(1:1)] of the same carboxylic host (1). The minor modification of the guest structure crucially affected the hydrogen bonding recognition pattern between given complementary groups, which demonstrates the sensitive balance of intermolecular interaction modes that must be controlled for successful crystal engineering and design of supramolecular compounds.
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