线性化玻尔兹曼碰撞算子:由连续内能变量模拟的多原子分子

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Niclas Bernhoff
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引用次数: 7

摘要

单种玻尔兹曼方程的线性化碰撞算子可以写成正乘法算子、碰撞频率和紧致积分算子的和。这一经典结果最近被推广到多组分混合物和多原子单种,多原子性由离散内能变量建模。本文证明了多原子单种积分算子的紧性,其中多原子性由一个连续的内能变量来建模,并且内部自由度大于或等于2。积分算子的项被证明是,或者是Hilbert-Schmidt积分算子的一致极限。线性化碰撞算子的自伴随性。对于类硬球和类截止模型的硬势,给出了碰撞频率的矫顽力,表明了线性化碰撞算子的弗雷德霍姆性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Linearized Boltzmann collision operator: II. Polyatomic molecules modeled by a continuous internal energy variable
The linearized collision operator of the Boltzmann equation for single species can be written as a sum of a positive multiplication operator, the collision frequency, and a compact integral operator. This classical result has more recently, been extended to multi-component mixtures and polyatomic single species with the polyatomicity modeled by a discrete internal energy variable. In this work we prove compactness of the integral operator for polyatomic single species, with the polyatomicity modeled by a continuous internal energy variable, and the number of internal degrees of freedom greater or equal to two. The terms of the integral operator are shown to be, or be the uniform limit of, Hilbert-Schmidt integral operators. Self-adjointness of the linearized collision operator follows. Coercivity of the collision frequency are shown for hard-sphere like and hard potential with cut-off like models, implying Fredholmness of the linearized collision operator.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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