{"title":"三嵌段共聚物溶液中胶束的形成","authors":"M. Monzen , T. Kawakatsu , M. Doi , R. Hasegawa","doi":"10.1016/S1089-3156(99)00052-5","DOIUrl":null,"url":null,"abstract":"<div><p><span>Using the self-consistent field treatment, we investigate the structures and the phase behavior of micelles formed in symmetric and asymmetric </span>triblock copolymer<span> solutions. We find that the asymmetry of the block copolymer lowers the critical micelle concentration due to the gain of the conformational entropy.</span></p></div>","PeriodicalId":100309,"journal":{"name":"Computational and Theoretical Polymer Science","volume":"10 3","pages":"Pages 275-280"},"PeriodicalIF":0.0000,"publicationDate":"2000-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1089-3156(99)00052-5","citationCount":"21","resultStr":"{\"title\":\"Micelle formation in triblock copolymer solutions\",\"authors\":\"M. Monzen , T. Kawakatsu , M. Doi , R. Hasegawa\",\"doi\":\"10.1016/S1089-3156(99)00052-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span>Using the self-consistent field treatment, we investigate the structures and the phase behavior of micelles formed in symmetric and asymmetric </span>triblock copolymer<span> solutions. We find that the asymmetry of the block copolymer lowers the critical micelle concentration due to the gain of the conformational entropy.</span></p></div>\",\"PeriodicalId\":100309,\"journal\":{\"name\":\"Computational and Theoretical Polymer Science\",\"volume\":\"10 3\",\"pages\":\"Pages 275-280\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2000-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1089-3156(99)00052-5\",\"citationCount\":\"21\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Computational and Theoretical Polymer Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1089315699000525\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Computational and Theoretical Polymer Science","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1089315699000525","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Using the self-consistent field treatment, we investigate the structures and the phase behavior of micelles formed in symmetric and asymmetric triblock copolymer solutions. We find that the asymmetry of the block copolymer lowers the critical micelle concentration due to the gain of the conformational entropy.
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