{"title":"Ni(II)与N- h, N- γ， S- γ， γ - γ donar原子作为二级配体的比较研究","authors":"A. Kumari","doi":"10.22271/27078221.2020.v1.i1a.9","DOIUrl":null,"url":null,"abstract":"In this paper a comparative study is carried out on binary, NiL 2 , and ternary NiAL complexes. Where A=2, 2 4 bipyridyl amine or 2.2 bipyridyl and L=N-N or N-Ō or S-Ō or Ō-Ō donating ligand. The order of stabilities of binary & ternary complexes is explained on the basicities of the ligand & ring size of the chelate. The sequence in order is explained in terms of M L π interaction, size of chelate ring & steric factor. The same order is followed both by ternary complexes and binary","PeriodicalId":14103,"journal":{"name":"International Journal of Materials Science and Engineering","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A comparative study of Ni(II) with N-H, N-ō, S-ō, ō-ō donar atoms as secondary ligand\",\"authors\":\"A. Kumari\",\"doi\":\"10.22271/27078221.2020.v1.i1a.9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this paper a comparative study is carried out on binary, NiL 2 , and ternary NiAL complexes. Where A=2, 2 4 bipyridyl amine or 2.2 bipyridyl and L=N-N or N-Ō or S-Ō or Ō-Ō donating ligand. The order of stabilities of binary & ternary complexes is explained on the basicities of the ligand & ring size of the chelate. The sequence in order is explained in terms of M L π interaction, size of chelate ring & steric factor. The same order is followed both by ternary complexes and binary\",\"PeriodicalId\":14103,\"journal\":{\"name\":\"International Journal of Materials Science and Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Materials Science and Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.22271/27078221.2020.v1.i1a.9\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Materials Science and Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22271/27078221.2020.v1.i1a.9","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A comparative study of Ni(II) with N-H, N-ō, S-ō, ō-ō donar atoms as secondary ligand
In this paper a comparative study is carried out on binary, NiL 2 , and ternary NiAL complexes. Where A=2, 2 4 bipyridyl amine or 2.2 bipyridyl and L=N-N or N-Ō or S-Ō or Ō-Ō donating ligand. The order of stabilities of binary & ternary complexes is explained on the basicities of the ligand & ring size of the chelate. The sequence in order is explained in terms of M L π interaction, size of chelate ring & steric factor. The same order is followed both by ternary complexes and binary
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