用于电化学传感器、光催化和抗氧化应用的氧化锌纳米颗粒支撑粘土矿物研究

Mylarappa M , N. Raghavendra , N.R. Bhumika , C.H. Chaithra , B.N. Nagalaxmi , K.N. Shravana Kumara
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引用次数: 0

摘要

鉴于目前的研究证明了粘土掺杂氧化锌复合材料的合成,我们提出了一种生产粘土-金属氧化物(粘土/氧化锌)的低成本方法。利用溶液燃烧技术,以柠檬酸作为燃料和络合剂,生产出粘土/氧化锌复合材料。通过 XRD 图可以看到所制得的粘土/氧化锌的六角形单胞结构。在 FE-SEM 显微照片中,可以看到注入氧化锌的粘土是均匀的球形氧化锌。研究了粘土/氧化锌的光催化活性在紫外线诱导的孔雀石绿染料光降解中的可能参与。90% 的降解率表明该复合材料具有出色的光催化降解能力。在 0.1 M KOH 电解液中,使用构建的电极对所得物质进行了电化学分析。它提高了传感器的能力,现在包括化学和生物分子传感器,并在基于循环伏安法的氧化还原电位研究中表现出色。为了有效评估化学合成的纳米氧化物在电化学、传感和光催化方面的应用,本研究打算创建一种以尿素为燃料合成粘土/氧化锌纳米复合材料的溶液燃烧程序。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study of ZnO nanoparticle-supported clay minerals for electrochemical sensors, photocatalysis, and antioxidant applications

In view of the current study's demonstration of the synthesis of clay-doped ZnO composites, we present a low-cost method for producing clay-metal oxide (clay/ZnO). Utilizing the solution combustion technique, a composite of clay/ZnO was produced utilizing citric acid as both a fuel and a complexing agent. The hexagonal unit cell structure of the created clay/ZnO may be seen using XRD patterns. The ZnO-infused clay was visible in FE-SEM micrographs as homogenous, sphere-shaped ZnO. The possible involvement of clay/ZnO photocatalytic activity in the UV-induced photodegradation of malachite green dye was investigated. The 90% degradation rate shows the composite's outstanding photocatalytic degradation capacity. The resulting substance was electrochemically analyzed using a constructed electrode in 0.1 M KOH electrolyte. It increased its sensor capabilities, which now include chemical and biomolecule sensors, and it excelled in cyclic voltammetry-based redox potential studies. To efficiently evaluate chemically synthesized NPs for electrochemical, sensing, and photocatalytic applications, this study intends to create a solution combustion procedure for the synthesis of clay/ZnO nanocomposite using urea as fuel.

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