{"title":"用热分析方法对白花菊和白花菊种子质量的研究","authors":"E. Zueva, S. Belopukhov, Ravil F. Baybekov","doi":"10.37952/ROI-JBC-01/20-64-12-45","DOIUrl":null,"url":null,"abstract":"The paper presents data on the study of the chemical composition of dill (Anethum graveolens L) using foliar treatment of vegetative plants with the growth-regulating agent Nicosulfuron [2-(4,6-dimethoxypyrimidin-2-ylcarbomoyl-sulfamoyl) -N,N-dimethylnicotinamide]. Field experiments were carried out at the agrobiological station of the Humanitarian and Technological University of the city of Orekhovo-Zuevo, Moscow Region in 2016-2018. The soil of the experimental plots is sod-podzolic medium loamy. Plants were treated with a solution of Nicosulfuron with a concentration of 0.1 g/l according to the active substance. It was found that foliar treatment of vegetative plants with a solution of 2-(4,6-dimethoxypyrimidin-2-ylcarbomoyl-sulfamoyl)-N,N-dimethylnico-tinamide led to a change in the concentrations of macrocomponents in the seeds of dill varieties Gribovsky and Lesnogorodsky. Differential thermal analysis of DTA) of dill seeds was carried out using a thermoanalytical complex based on a derivatograph. The sample heating rate in a platinum crucible was 5, 10, and 20 degrees per minute. The DTA method showed a significant difference in the component composition of the organic matter of seeds of both varieties. 6 organic components can be grouped into two groups – with thermal decomposition temperatures of 200-400 °C and 400-600 °C. The treatment with Nicosulfuron leads to a shift in the accumulation of synthesized spare components of seeds towards easily degradable (up to 400 °C) components. This treatment effect is manifested in the fact that in the total mass of organic components of dill seeds (at the level of 87%), the fraction of readily decomposable organic matter is 64-70% for both varieties. In the control variant, without treatment with the drug, the biosynthesis of hardly degradable components, probably having a high molecular weight, and for high-molecular compounds having a high degree of polymerization, occurs. At the same time, the total activation energy for organic compounds in the control is 30-40% higher compared to the samples that were treated with Nicosulfuron.","PeriodicalId":9405,"journal":{"name":"Butlerov Communications","volume":"121 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2020-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigation of the quality of seeds of Anethum graveolens varieties Gribovsky and Lesnogorodsky by method of thermal analysis\",\"authors\":\"E. Zueva, S. Belopukhov, Ravil F. Baybekov\",\"doi\":\"10.37952/ROI-JBC-01/20-64-12-45\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The paper presents data on the study of the chemical composition of dill (Anethum graveolens L) using foliar treatment of vegetative plants with the growth-regulating agent Nicosulfuron [2-(4,6-dimethoxypyrimidin-2-ylcarbomoyl-sulfamoyl) -N,N-dimethylnicotinamide]. Field experiments were carried out at the agrobiological station of the Humanitarian and Technological University of the city of Orekhovo-Zuevo, Moscow Region in 2016-2018. The soil of the experimental plots is sod-podzolic medium loamy. Plants were treated with a solution of Nicosulfuron with a concentration of 0.1 g/l according to the active substance. It was found that foliar treatment of vegetative plants with a solution of 2-(4,6-dimethoxypyrimidin-2-ylcarbomoyl-sulfamoyl)-N,N-dimethylnico-tinamide led to a change in the concentrations of macrocomponents in the seeds of dill varieties Gribovsky and Lesnogorodsky. Differential thermal analysis of DTA) of dill seeds was carried out using a thermoanalytical complex based on a derivatograph. The sample heating rate in a platinum crucible was 5, 10, and 20 degrees per minute. The DTA method showed a significant difference in the component composition of the organic matter of seeds of both varieties. 6 organic components can be grouped into two groups – with thermal decomposition temperatures of 200-400 °C and 400-600 °C. The treatment with Nicosulfuron leads to a shift in the accumulation of synthesized spare components of seeds towards easily degradable (up to 400 °C) components. This treatment effect is manifested in the fact that in the total mass of organic components of dill seeds (at the level of 87%), the fraction of readily decomposable organic matter is 64-70% for both varieties. In the control variant, without treatment with the drug, the biosynthesis of hardly degradable components, probably having a high molecular weight, and for high-molecular compounds having a high degree of polymerization, occurs. At the same time, the total activation energy for organic compounds in the control is 30-40% higher compared to the samples that were treated with Nicosulfuron.\",\"PeriodicalId\":9405,\"journal\":{\"name\":\"Butlerov Communications\",\"volume\":\"121 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-12-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Butlerov Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.37952/ROI-JBC-01/20-64-12-45\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Butlerov Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.37952/ROI-JBC-01/20-64-12-45","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
本文介绍了生长调节剂nico磺隆[2-(4,6-二甲氧基嘧啶-2-酰基氨基磺基)- n, n-二甲基烟酰胺]对营养植物叶面处理莳萝(Anethum graveolens L)化学成分的研究数据。2016-2018年,在莫斯科州奥列霍沃-祖埃沃市人道主义和技术大学的农业生物站进行了实地实验。试验田土壤为灰化土中壤土。用浓度为0.1 g/l的尼可隆溶液处理植株。研究发现,营养植物叶面处理2-(4,6-二甲氧基吡啶-2-酰基氨基磺酰基)- n, n-二甲基nico-tinamide溶液可改变莳蕾品种Gribovsky和Lesnogorodsky种子中主要成分的浓度。采用基于衍生物的热分析配合物对莳萝种子的DTA进行了差热分析。样品在铂坩埚中的加热速率为每分钟5度、10度和20度。DTA分析结果表明,两品种种子有机质组分组成差异显著。6种有机组分可分为热分解温度200-400℃和400-600℃两组。用尼科磺隆处理导致种子合成备用成分的积累转向易于降解(高达400°C)的成分。这种处理效果表现在两个品种莳萝种子有机成分总质量(87%)中,易分解有机质的比例为64-70%。在对照变异体中,不经药物处理,发生难以降解成分的生物合成,可能具有高分子量,以及具有高度聚合的高分子化合物。同时,对照样品中有机化合物的总活化能比经尼磺隆处理的样品高30-40%。
Investigation of the quality of seeds of Anethum graveolens varieties Gribovsky and Lesnogorodsky by method of thermal analysis
The paper presents data on the study of the chemical composition of dill (Anethum graveolens L) using foliar treatment of vegetative plants with the growth-regulating agent Nicosulfuron [2-(4,6-dimethoxypyrimidin-2-ylcarbomoyl-sulfamoyl) -N,N-dimethylnicotinamide]. Field experiments were carried out at the agrobiological station of the Humanitarian and Technological University of the city of Orekhovo-Zuevo, Moscow Region in 2016-2018. The soil of the experimental plots is sod-podzolic medium loamy. Plants were treated with a solution of Nicosulfuron with a concentration of 0.1 g/l according to the active substance. It was found that foliar treatment of vegetative plants with a solution of 2-(4,6-dimethoxypyrimidin-2-ylcarbomoyl-sulfamoyl)-N,N-dimethylnico-tinamide led to a change in the concentrations of macrocomponents in the seeds of dill varieties Gribovsky and Lesnogorodsky. Differential thermal analysis of DTA) of dill seeds was carried out using a thermoanalytical complex based on a derivatograph. The sample heating rate in a platinum crucible was 5, 10, and 20 degrees per minute. The DTA method showed a significant difference in the component composition of the organic matter of seeds of both varieties. 6 organic components can be grouped into two groups – with thermal decomposition temperatures of 200-400 °C and 400-600 °C. The treatment with Nicosulfuron leads to a shift in the accumulation of synthesized spare components of seeds towards easily degradable (up to 400 °C) components. This treatment effect is manifested in the fact that in the total mass of organic components of dill seeds (at the level of 87%), the fraction of readily decomposable organic matter is 64-70% for both varieties. In the control variant, without treatment with the drug, the biosynthesis of hardly degradable components, probably having a high molecular weight, and for high-molecular compounds having a high degree of polymerization, occurs. At the same time, the total activation energy for organic compounds in the control is 30-40% higher compared to the samples that were treated with Nicosulfuron.