[热释光理论]。

M. Böhm
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引用次数: 72

摘要

刺激辐射与物质的相互作用产生的缺陷可分为两类:2.电子缺陷;离子缺陷。缺陷的形成本质上是由电子过程和弹性冲击决定的。以热形式提供的能量使热刺激成为可能,热刺激的概率用玻尔兹曼因子来表示。而经典的解释是基于热力学或统计学的考虑,量子力学计算涉及到从陷阱的非辐射跃迁。对于辐射复合,一个保证能量和冲量守恒的选择规则是有效的。热释光的现象学描述利用了非平稳情况下的动力学过程,并允许在简单模型中确定陷阱参数,如活化能或指数前因子。通过引入热分离的疏水层,可以扩展简单的模型。利用模拟计算机对动力学平衡方程进行精确求解,得到的辉光曲线与实验曲线吻合较好。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
[The theory of thermoluminescence].
The interaction of stimulating radiation with matter produces defects which can be divided into two groups: 1. electronic defects, 2. ionic defects. The formation of defects is essentially determined by electronic processes and elastic impacts. The supply of energy in the form of heat makes possible a thermal stimulation the probability of which is characterized by a Boltzmann factor. Whereas the classical explications are based on thermodynamic or statistical considerations, the quantum mechanical calculation relates to non-radiative transitions from traps. For the radiating recombination a selective rule is valid which guarantees the conservation of energy and impulse. The phenomenological description of thermoluminescence makes use of the kinetic processes in the non-stationary case and allows in simple models the determination of trap parameters, such as activation energy or pre-exponential factor. The simple models can be extended by introducing thermally separated trap levels. If the kinetic balance equations are solved exactly with the aid of an analogic computer, the simulated Glow curves show a good correspondence with experimental curves.
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