{"title":"3-烷基-1-烯丙醛的重排:紫锥菊素类化合物生物发生的一个模式反应","authors":"G. Casnati, A. Pochini","doi":"10.1039/C29700001328","DOIUrl":null,"url":null,"abstract":"The reactivity of 3-alkyl-1-allylindoles as model systems in the biogenesis and synthesis of the echinulin-type compounds has been studied: in the presence of acids the crotyl and γγ-dimethylallyl groups migrate from the 1- to the 2-position of the indole nucleus with a partial allylic rearrangement.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"48 1","pages":"1328-1329"},"PeriodicalIF":0.0000,"publicationDate":"1974-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"21","resultStr":"{\"title\":\"Rearrangement of 3-alkyl-1-allylindoles: a model reaction for the biogenesis of echinulin-type compounds\",\"authors\":\"G. Casnati, A. Pochini\",\"doi\":\"10.1039/C29700001328\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The reactivity of 3-alkyl-1-allylindoles as model systems in the biogenesis and synthesis of the echinulin-type compounds has been studied: in the presence of acids the crotyl and γγ-dimethylallyl groups migrate from the 1- to the 2-position of the indole nucleus with a partial allylic rearrangement.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"48 1\",\"pages\":\"1328-1329\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1974-06-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"21\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29700001328\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29700001328","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Rearrangement of 3-alkyl-1-allylindoles: a model reaction for the biogenesis of echinulin-type compounds
The reactivity of 3-alkyl-1-allylindoles as model systems in the biogenesis and synthesis of the echinulin-type compounds has been studied: in the presence of acids the crotyl and γγ-dimethylallyl groups migrate from the 1- to the 2-position of the indole nucleus with a partial allylic rearrangement.
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