链连接的富勒烯供体二对体[60]

Fullerene Science and Technology Pub Date : 2001-08-31 DOI:10.1081/FST-100107149

Jian-Yu Zheng, Shuichi Noguchi, Kenjo Miyauchi, Masahiro Hamada, K. Kinbara, K. Saigo

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引用次数: 2

摘要

通过[60]富勒烯与系链双丙二酸酯的双环丙烷化反应，合成了一系列[60]富勒烯双加合物，其上有一个富π电子的芳香环作为正面排列的给体。其中一种双加合物表现出光诱导的分子内电子转移，导致其荧光在极性溶剂中急剧猝灭。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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TETHER-LINKED [60]FULLERENE-DONOR DYADS

A series of [60]fullerene bis-adducts having a π-electron-rich aromatic ring as a donor in a face-to-face arrangement were synthesized by the bis-cyclopropanation of [60]fullerene with tether-linked bis-malonates. One of the bis-adducts showed a photoinduced intramolecular electron transfer which caused the dramatic quenching of its fluorescence in a polar solvent.

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Fullerene Science and Technology

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