聚丙烯/玻璃纤维/乙丙二烯三元复合材料的矫形助剂热成型性能的改善

Sonu Raghvan, Prachi Singhal, R. Diwan, S. Rattan
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引用次数: 2

摘要

本文研究了聚丙烯/玻璃纤维/乙丙二烯橡胶(PP/GF/EPDM)三元复合材料的矫形应用。在双螺杆挤出机中,采用熔融共混法制备了不同掺量的GF和EPDM的PP/GF和PP/GF/EPDM复合材料。采用顺丁烯二酸酐接枝聚丙烯(PP-g- mah)作为相容剂。通过扫描电镜(SEM)对复合材料的形貌进行了表征。根据ASTM标准研究了复合材料的力学性能,并与市场上昂贵的商用矫形材料进行了比较。使用GF作为增强纤维的缺点是复合材料的冲击和热成型性能的显著损失。加入三元乙丙橡胶作为弹性体是提高PP/GF复合材料抗冲击和伸长率的一种很有前途的方法。然而,EPDM导致拉伸强度和模量同时下降。因此,优化了GFs和EPDM在复合材料中的比例,以获得具有适当的拉伸和弯曲性能的矫正材料,以获得更长的耐用性,抗断裂的高冲击,以及易于通过热成型加工的有限断裂伸长率。所研制的PP/GF/EPDM复合材料具有良好的拉伸和冲击性能,具有作为低成本矫形材料的应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Polypropylene/glass fiber/ethylene propylene diene ternary composites with improved thermoforming properties for orthotic aids
In the present work, Polypropylene/Glass fiber/ethylene propylene diene rubber (PP/GF/EPDM) ternary composites were developed for orthotic applications. A series of PP/GF and PP/GF/EPDM composites with varied amount of GF and EPDM were fabricated through melt-blending process in a twin screw extruder. Maleic anhydride grafted PP (PP-g-MAH) was used as compatibilizer. The composites were characterized for its morphology through scanning electron microscopy (SEM). Mechanical properties of the composites were investigated as per ASTM standards and were compared with the costly commercial orthotic materials available in the market. The drawback of using GF as reinforcement fibers is the significant loss of impact and thermoforming properties of the composites. Incorporation of EPDM as elastomer is a promising approach to improve both impact and elongation of PP/GF composites. However, EPDM results in simultaneous decrease in the tensile strength and modulus properties. Thus, the proportion of GFs and EPDM were optimized in the composites to obtain an orthotic material with appropriate tensile and flexural properties for longer durability, high impact for its resistance to fracture and a limiting elongation at break for easy processing through thermoforming. The developed PP/GF/EPDM composites with balanced tensile and impact properties shows potential application as low cost orthotic material.
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