{"title":"银催化叠氮化物-炔环加成:无铜合成1,4-二取代1,2,3-三唑的方法","authors":"Jasmin Sultana, D. Sarma","doi":"10.1080/01614940.2019.1673443","DOIUrl":null,"url":null,"abstract":"ABSTRACT This review mainly focuses on purely Ag-catalyzed 1,3-dipolar azide-alkyne cycloaddition (AgAAC) so called click reaction to synthesize 1,4-regioisomers of 1,2,3-triazoles. The most established catalyst Cu (I) developed by Fokin–Sharpless and Meldal group in 2002 for AAC reaction have been further extended to different other transition metal catalysts because of certain limitations of CuAAC methods. Among different transition metal catalyzed methods, AgAAC is the most studied one having same electronic configuration, d10 (AgI) with that of CuI and shows high catalytic performance.","PeriodicalId":9647,"journal":{"name":"Catalysis Reviews","volume":"42 1","pages":"117 - 96"},"PeriodicalIF":0.0000,"publicationDate":"2020-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"22","resultStr":"{\"title\":\"Ag-catalyzed azide-alkyne cycloaddition: copper free approaches for synthesis of 1,4-disubstituted 1,2,3-triazoles\",\"authors\":\"Jasmin Sultana, D. Sarma\",\"doi\":\"10.1080/01614940.2019.1673443\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT This review mainly focuses on purely Ag-catalyzed 1,3-dipolar azide-alkyne cycloaddition (AgAAC) so called click reaction to synthesize 1,4-regioisomers of 1,2,3-triazoles. The most established catalyst Cu (I) developed by Fokin–Sharpless and Meldal group in 2002 for AAC reaction have been further extended to different other transition metal catalysts because of certain limitations of CuAAC methods. Among different transition metal catalyzed methods, AgAAC is the most studied one having same electronic configuration, d10 (AgI) with that of CuI and shows high catalytic performance.\",\"PeriodicalId\":9647,\"journal\":{\"name\":\"Catalysis Reviews\",\"volume\":\"42 1\",\"pages\":\"117 - 96\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-01-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"22\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Reviews\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/01614940.2019.1673443\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Reviews","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/01614940.2019.1673443","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Ag-catalyzed azide-alkyne cycloaddition: copper free approaches for synthesis of 1,4-disubstituted 1,2,3-triazoles
ABSTRACT This review mainly focuses on purely Ag-catalyzed 1,3-dipolar azide-alkyne cycloaddition (AgAAC) so called click reaction to synthesize 1,4-regioisomers of 1,2,3-triazoles. The most established catalyst Cu (I) developed by Fokin–Sharpless and Meldal group in 2002 for AAC reaction have been further extended to different other transition metal catalysts because of certain limitations of CuAAC methods. Among different transition metal catalyzed methods, AgAAC is the most studied one having same electronic configuration, d10 (AgI) with that of CuI and shows high catalytic performance.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
