{"title":"环氧化合物的扩环羰基化反应","authors":"J. W. Kramer, J. M. Rowley, G. Coates","doi":"10.1002/0471264180.OR086.01","DOIUrl":null,"url":null,"abstract":"This review summarizes the field of metal-catalyzed ring-expanding carbonylation of epoxides. Specifically, epoxide carbonylation to -, -, and -lactones is reviewed, in addition to epoxide carbonylation to succinic anhydrides, 1,3-oxazinane-2,4-diones and 1,3-oxathiolan-2-ones. For each reaction, the mechanism of catalysis and control of stereochemistry are discussed and the scope and limitations of the catalysts are considered. Experimental conditions and procedures are also presented. In addition, non-carbonylative routes preparing similar products are compared. \n \n \nKeywords: \n \nCarbonylation; \ncarbon-carbon bond formation; \ncarbon monoxide; \ncatalysis; \nepoxide; \nlactone; \nring-expansion; \nsuccinic anhydride","PeriodicalId":19539,"journal":{"name":"Organic Reactions","volume":"16 1","pages":"1-104"},"PeriodicalIF":0.0000,"publicationDate":"2015-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Ring‐Expanding Carbonylation of Epoxides\",\"authors\":\"J. W. Kramer, J. M. Rowley, G. Coates\",\"doi\":\"10.1002/0471264180.OR086.01\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This review summarizes the field of metal-catalyzed ring-expanding carbonylation of epoxides. Specifically, epoxide carbonylation to -, -, and -lactones is reviewed, in addition to epoxide carbonylation to succinic anhydrides, 1,3-oxazinane-2,4-diones and 1,3-oxathiolan-2-ones. For each reaction, the mechanism of catalysis and control of stereochemistry are discussed and the scope and limitations of the catalysts are considered. Experimental conditions and procedures are also presented. In addition, non-carbonylative routes preparing similar products are compared. \\n \\n \\nKeywords: \\n \\nCarbonylation; \\ncarbon-carbon bond formation; \\ncarbon monoxide; \\ncatalysis; \\nepoxide; \\nlactone; \\nring-expansion; \\nsuccinic anhydride\",\"PeriodicalId\":19539,\"journal\":{\"name\":\"Organic Reactions\",\"volume\":\"16 1\",\"pages\":\"1-104\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2015-01-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Organic Reactions\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/0471264180.OR086.01\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Reactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/0471264180.OR086.01","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
This review summarizes the field of metal-catalyzed ring-expanding carbonylation of epoxides. Specifically, epoxide carbonylation to -, -, and -lactones is reviewed, in addition to epoxide carbonylation to succinic anhydrides, 1,3-oxazinane-2,4-diones and 1,3-oxathiolan-2-ones. For each reaction, the mechanism of catalysis and control of stereochemistry are discussed and the scope and limitations of the catalysts are considered. Experimental conditions and procedures are also presented. In addition, non-carbonylative routes preparing similar products are compared.
Keywords:
Carbonylation;
carbon-carbon bond formation;
carbon monoxide;
catalysis;
epoxide;
lactone;
ring-expansion;
succinic anhydride
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
