线性物体有限晶粒生长中的渗透和干扰特性

IF 0.2 Q4 CHEMISTRY, MULTIDISCIPLINARY
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引用次数: 0

摘要

纳米晶体的物理和化学性质高度依赖于形状,形状控制变得非常重要。种子生长法使种子以预定的方式生长。我们已经提出了这样的模型,可以在三角形晶格和不同的生长形状上再现颗粒生长。然而,在本文中,我们引入了对种子生长到一定长度的限制。这种方法可用于所有种子的生长必须限制在相同的长度,或具有不同生长限制的混合物。主要目的是研究生长极限如何影响渗透阈值和干扰密度,以及大型物体是否显著影响渗透阈值。我们使用一种自我避免随机游走的方法来填充三角形晶格的节点,从而生成针状物体(k-mers)。对象可以增长,直到达到增长极限k',即属于一个对象的最大晶格节点数。当k′≥10时,所有研究的种子密度都达到了渗滤。我们得到,当k′≥10k时,渗透阈值和干扰密度的值是相同的,在此值以上,无论生长极限如何,渗透阈值和干扰都保持不变。我们的结果还表明,当允许显著增长时,长对象非常罕见,不会影响结果。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Percolation and jamming properties in limited grain growth of linear objects
The physical and chemical properties of the nanocrystals are highly shape dependent, and shape control has become very important. The seeded growth method enables seeds to grow in a predetermined way. We have already proposed such amodel that can reproduce the granular growth on a triangular lattice and for different growth shapes. In this paper, however, we have introduced a limitation on seed growth up to a certain length. This method can be used when the growth of all seeds have to be limited to the same length, or for a mixture with the different growth limits.The main goal is to investigate how the growing limits affect the values of the percolation threshold and jamming density, and whether large objects significantly affect the percolation threshold. We used growing needle-shaped objects (k-mers) made by a self-avoiding random walk filling the nodes of the triangular lattice. Objects can grow until they reach the growth limit k' defined as the maximum number of lattice nodes belonging to one object. For k' ≥10 percolation is reached for all investigated seed densities. We obtained that the values of the percolation threshold and jamming density are identical for k' ≥10k .Above these values, the percolation threshold and jamming remain unchanged, regardless of the growth limit.Our results also show that when significant growth is allowed, long objects are very rare and do not influence the results.
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来源期刊
Glasnik Hemicara i Tehnologa Bosne i Hercegovine
Glasnik Hemicara i Tehnologa Bosne i Hercegovine CHEMISTRY, MULTIDISCIPLINARY-
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