平衡、定量和定义氧化还原反应的电荷法

Pong Kau Yuen, C. M. Lau
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引用次数: 1

摘要

定义和平衡氧化还原反应是化学研究中的核心知识和技能。完成这两项任务最常用的方法是氧化数法,它将数学运算和氧化数的应用相结合。但是,当氧化值未知时,则不适用。代数方法可以在数学上平衡所有的化学反应,但它们不能在化学上定义氧化还原反应。本文探讨了平衡、定量和定义氧化还原反应的电荷法。这种方法只需要原子和电荷的平衡。不需要测定氧化值或计算转移电子的数目。在氧化数不确定和两组以上氧化还原对存在的复杂情况下,它能有效地工作。此外,氧化还原对的净电荷可以作为一个计数概念来确定它的转移电子数和氧化数的变化。电荷法还开创了一种新的电荷模型,补充了传统的电子模型和氧化数模型,用于定义氧化还原反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Electrical Charge Method for Balancing, Quantifying, and Defining Redox Reactions
Defining and balancing redox reactions are core knowledge and skills in the study of chemistry. The most common method to perform these two tasks is the oxidation number method, which combines mathematical operations and application of oxidation number. However, when oxidation number is not known, it is not applicable. Algebraic methods can balance all chemical reactions mathematically, but they cannot define redox reactions chemically. This article explores the electrical charge method for balancing, quantifying, and defining redox reactions. This method only requires the balancing of atoms and electrical charges. There is no need to determine oxidation number or count the number of transferred electrons. It works effectively in complicated cases where oxidation number is uncertain and where there are more than two sets of redox couples. Furthermore, the net-charge of a redox couple can function as a counting concept to determine its number of transferred electrons and change of oxidation numbers. The electrical charge method also initiates a new charge model, which complements the conventional electron model and oxidation number model, for defining redox reactions.
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