22章。金属-有机框架的杂化作为有组织的超分子纳米反应器

L. Kustov, V. Isaeva
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引用次数: 0

摘要

从不同结构类型的金属有机骨架多孔结构的非共价相互作用和分子约束的角度出发,考虑了将具有杯芳烃、冠醚、酞菁和卟啉等包封结构的金属有机骨架(MOFs)杂化物作为纳米反应器或纳米容器进行特定催化反应的概念。这种材料可称为“俄罗斯套娃式金属有机框架”。控制这种相互作用是提高催化剂效率和吸附剂性能的关键。设计“绿色”和健壮的mof是至关重要的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
CHAPTER 22. Hybrids of Metal–Organic Frameworks as Organized Supramolecular Nano-reactors
The concept of using hybrids of metal–organic frameworks (MOFs) with encapsulated structures, such as calixarenes, crown ethers, phthalocyanines and porphyrins, as nano-reactors or nano-containers for specific catalytic reactions is considered from the point of view of noncovalent interactions and molecular confinement in the porous architecture of MOFs of different structural types. Materials of this kind can be called “Russian matryoshka-type metal organic frameworks.” Controlling such interactions provides a key to enhancement of the efficiency of the catalysts and performance of adsorbents. The design of “green” and robust MOFs is of prime importance.
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