含正构烷醇二元混合物体积行为研究的理论与实验方法

Mohammad Almasi
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引用次数: 0

摘要

本文通过在T= 323.15 K时测量密度,研究了二甲苯与选定的1-烷醇(1-丁醇至1-辛醇)二元混合物中的分子相互作用。根据实验数据,计算了过量摩尔体积。根据二元液体系统中物理-化学相互作用的类型和大小来解释所获得的数据。在这个意义上,PC-SAFT被用来关联二元混合物的体积行为。模型的相关值令人满意,所得数据在不确定范围内。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Theoretical and Experimental Methods for Studying Volumetric Behavior of Binary mixtures Containing Normal Alkanols
In this paper, molecular interactions in the binary mixtures composed of a xylene and selected 1-alkanol (1-butanol up to 1-octanol) were investigated by measurement of the density at T= 323.15 K. From the experimental data, excess molar volumes were calculated. Obtained data were interpreted based on the type and magnitude of the physico-chemical interactions in the binary liquid systems. In this sense, PC-SAFT was used to correlate the volumetric behavior of binary mixtures. The correlated values of the model were satisfactory and the obtained data are within the uncertainty region.
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