D. Barr, W. Clegg, Lucy Cowton, Lynne Horsburgh, Fiona M. Mackenzie, R. Mulvey
{"title":"苯胺锂与聚苯胺配合:期望是一个简单的单体,但实际上是一个奇怪的三核组合物,由三、四和五坐标锂组成","authors":"D. Barr, W. Clegg, Lucy Cowton, Lynne Horsburgh, Fiona M. Mackenzie, R. Mulvey","doi":"10.1039/C39950000891","DOIUrl":null,"url":null,"abstract":"Lithium structural chemistry continues to surprise as highlighted here by the reaction of BunLi, aniline and pmdeta, which by analogy with related systems, should yield a simple monomeric complex, when, in fact, an unprecedented trinuclear formulation is produced; in contrast, the corresponding Na system falls into line with predictions, in yielding a dimeric product.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"77 1","pages":"891-892"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"15","resultStr":"{\"title\":\"Lithium anilide complexed by pmdeta: expectation of a simple monomer, but in reality an odd trinuclear composition combining three-, four- and five-coordinate lithium\",\"authors\":\"D. Barr, W. Clegg, Lucy Cowton, Lynne Horsburgh, Fiona M. Mackenzie, R. Mulvey\",\"doi\":\"10.1039/C39950000891\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Lithium structural chemistry continues to surprise as highlighted here by the reaction of BunLi, aniline and pmdeta, which by analogy with related systems, should yield a simple monomeric complex, when, in fact, an unprecedented trinuclear formulation is produced; in contrast, the corresponding Na system falls into line with predictions, in yielding a dimeric product.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"77 1\",\"pages\":\"891-892\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"15\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950000891\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950000891","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Lithium anilide complexed by pmdeta: expectation of a simple monomer, but in reality an odd trinuclear composition combining three-, four- and five-coordinate lithium
Lithium structural chemistry continues to surprise as highlighted here by the reaction of BunLi, aniline and pmdeta, which by analogy with related systems, should yield a simple monomeric complex, when, in fact, an unprecedented trinuclear formulation is produced; in contrast, the corresponding Na system falls into line with predictions, in yielding a dimeric product.