{"title":"影响氢化铝溶液稳定性的因素","authors":"D. C. Ayres, R. Sawdaye","doi":"10.1039/J39710000044","DOIUrl":null,"url":null,"abstract":"The loss of reducing power of solutions of this reagent in ethers is shown to depend on both aggregation and solvolysis. The former is dominant at higher concentrations and at lower temperatures, whereas the latter controls the rate of inactivation of dilute solutions.","PeriodicalId":17245,"journal":{"name":"Journal of The Chemical Society C: Organic","volume":"61 1","pages":"44-46"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Factors which affect the stability of aluminium hydride solutions\",\"authors\":\"D. C. Ayres, R. Sawdaye\",\"doi\":\"10.1039/J39710000044\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The loss of reducing power of solutions of this reagent in ethers is shown to depend on both aggregation and solvolysis. The former is dominant at higher concentrations and at lower temperatures, whereas the latter controls the rate of inactivation of dilute solutions.\",\"PeriodicalId\":17245,\"journal\":{\"name\":\"Journal of The Chemical Society C: Organic\",\"volume\":\"61 1\",\"pages\":\"44-46\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society C: Organic\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J39710000044\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society C: Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J39710000044","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Factors which affect the stability of aluminium hydride solutions
The loss of reducing power of solutions of this reagent in ethers is shown to depend on both aggregation and solvolysis. The former is dominant at higher concentrations and at lower temperatures, whereas the latter controls the rate of inactivation of dilute solutions.