环三咪唑基CuI和AgI配位聚合物的不同发射性质:QTAIM和IQA研究

Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials Pub Date : 2021-11-05 DOI:10.1107/S2052520621009707

A. Forni, E. Cariati, L. Carlucci, E. Lucenti, D. Marinotto, S. Pieraccini, M. Sironi

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引用次数: 2

摘要

AgI和CuI一维和三维配位聚合物发射态的不同性质可以用Cu-N键相对于Ag-N键更高的共价键来解释。

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Interpreting the different emissive properties of cyclic triimidazole-based CuI and AgI coordination polymers: a QTAIM and IQA study

The different nature of the emissive states of AgI and CuI one- and three-dimensional coordination polymers is here explained by a higher covalent character of the Cu—N bond with respect to the Ag—N one.

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Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials

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