赤泥在地聚合物砂浆混合物中的应用

Jelena Bijeljić, Nenad Stojkovic, Jovan Mišić
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摘要

常用的废物处理技术往往非常昂贵,而且往往难以获得。如今,数十亿吨有价值的废物被存放在垃圾填埋场,而没有利用潜力。事实上,总二氧化碳排放量的5%到10%来自土木工程,实际上来自水泥的生产,这意味着有必要寻找一些替代材料。碱活化材料-地聚合物是为了防止二氧化碳排放和利用废料而产生的。地聚合物是一种叫做地聚合的化学过程的结果。它们是为了促进防火而开发的,但在实验室测试中观察到它们的许多好处。工业副产品等材料可作为粘结材料,因为它们的化学结构富含硅铝化合物。就像在众所周知的建筑材料中一样,不同粘结材料的应用会导致材料结构的不同。在地聚合物混合物的生产过程中,粘结剂和碱活化剂比传统建筑材料需要更多的步骤:如粘结剂材料的混合,液相的溶解等,但最终的碳排放量比其他混合物低几倍。很明显地,地聚合物的最大好处是其生态方面。本文介绍了地聚合物混合物的物理、力学和耐久性特性的测试结果。以粉煤灰为主要原料,掺加赤泥代替部分原料。所有地聚合物砂浆混合料在抗压和弯曲强度方面都满足基本要求。在霜冻和解冻的情况下,测试持续了25个周期。可以得出结论,仅在用15%赤泥配制的混合物和标准龙样品中,阻力系数在抗弯强度方面大于75%。通过对抗压强度参数的计算,得出了掺加赤泥和粉煤灰的地聚合物砂浆的抗冻融性能可达25次。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
USAGE OF RED MUD IN GEOPOLYMER MORTAR MIXTURES
Popular techniques of waste treatment are often very expensive and often difficult to access.Nowadays, billions of tons of valuable waste material are deposited in landfills without using potential. The factthat five to ten percent of the total carbon dioxide emissions coming from civil engineering, actually from theproduction of cement, means that it is necessary to find some alternative materials. Alkali-activated materials -geopolymers are created in order to prevent carbon dioxide emission and to use waste materials. Geopolymersare the result of a chemical process called geopolymerization. They were developed in order to promote fireprotection, but their numerous benefits were observed during the laboratory tests. Materials such as industrialby-products might be used as a binder material because their chemical structure is rich in aluminosilicatecompounds. As in well-known building materials, as it is here, the application of different binder materialsmakes a difference in the material structure. During the process of geopolymer mixtures production, binders andalkali activators required more steps than traditional building materials: like blending the binder materials,dissolving the liquid phase, etc., but in the end, the carbon emission is a few times lower when compared toothers mixtures. It is clear that the greatest benefit of geopolymer is their ecological aspects.The paper presents the results of testing the physical, mechanical, and durability characteristics of geopolymermixtures. Fly ash was used as the primary material, while its partial replacement was made with the addition ofred mud. All geopolymer mortar mixes meet the basic requirements in terms of compressive and flexuralstrengths.The testing was continued on frost and thaw up to twenty-five cycles. It can be concluded that the coefficient ofresistance, in terms of flexural strength is greater than seventy-five percent only in the mixtures made withfifteen percent red mud and on the etalon sample. By calculating the compressive strength resistance parameter,it was concluded that all samples of geopolymer mortar that are made of fly ash and with the addition of redmud are freezing and thawing resistant up to twenty-five cycles.
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