{"title":"四氢吡喃苷的酸水解:2-甲基化和3-羟基化对水解速率的影响","authors":"Robert V. Petersen","doi":"10.1002/jps.3030491204","DOIUrl":null,"url":null,"abstract":"<div><p>A series of methyl glycosides (acetals and ketals) analogous to aldopyranosides, ketopyranosides, and their 3-hydroxy analogs (tetrahydropyran, 2-methyl-tetrahydropyran, and 3-hydroxyl derivatives of these compounds) were synthesized, subjected to acids of various concentrations, and their rates of hydrolysis determined spectrophotometrically.</p></div>","PeriodicalId":100839,"journal":{"name":"Journal of the American Pharmaceutical Association (Scientific ed.)","volume":"49 12","pages":"Pages 750-755"},"PeriodicalIF":0.0000,"publicationDate":"1960-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/jps.3030491204","citationCount":"3","resultStr":"{\"title\":\"Acid hydrolysis of tetrahydropyranyl glycosides: Effects of 2-methylation and 3-hydroxylation on rate of hydrolysis\",\"authors\":\"Robert V. Petersen\",\"doi\":\"10.1002/jps.3030491204\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A series of methyl glycosides (acetals and ketals) analogous to aldopyranosides, ketopyranosides, and their 3-hydroxy analogs (tetrahydropyran, 2-methyl-tetrahydropyran, and 3-hydroxyl derivatives of these compounds) were synthesized, subjected to acids of various concentrations, and their rates of hydrolysis determined spectrophotometrically.</p></div>\",\"PeriodicalId\":100839,\"journal\":{\"name\":\"Journal of the American Pharmaceutical Association (Scientific ed.)\",\"volume\":\"49 12\",\"pages\":\"Pages 750-755\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1960-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1002/jps.3030491204\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the American Pharmaceutical Association (Scientific ed.)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0095955315300044\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the American Pharmaceutical Association (Scientific ed.)","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0095955315300044","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Acid hydrolysis of tetrahydropyranyl glycosides: Effects of 2-methylation and 3-hydroxylation on rate of hydrolysis
A series of methyl glycosides (acetals and ketals) analogous to aldopyranosides, ketopyranosides, and their 3-hydroxy analogs (tetrahydropyran, 2-methyl-tetrahydropyran, and 3-hydroxyl derivatives of these compounds) were synthesized, subjected to acids of various concentrations, and their rates of hydrolysis determined spectrophotometrically.
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