Nikhat G. Sheikh , Vijay M. Tangde , Niraj T. Khaty , Sudhakar S. Dhondge , Alka S. Dhondge
{"title":"l -瓜氨酸在不同温度的尿素和葡萄糖水溶液中的体积和声学研究","authors":"Nikhat G. Sheikh , Vijay M. Tangde , Niraj T. Khaty , Sudhakar S. Dhondge , Alka S. Dhondge","doi":"10.1016/j.ctta.2022.100061","DOIUrl":null,"url":null,"abstract":"<div><p>Density <span><math><mrow><mo>(</mo><mi>ρ</mi><mo>)</mo></mrow></math></span> and speed of sound <span><math><mrow><mo>(</mo><mi>u</mi><mo>)</mo></mrow></math></span> values of L-Citrulline in aqueous solution, 0.06 mol·kg<sup>−1</sup> aqueous Urea and aqueous 0.06 mol·kg<sup>−1</sup> Dextrose solutions have been measured at <em>T</em> = (288.15, 293.15, 298.15, 303.15, 308.15, 313.15 and 318.15) K within the concentration range of (0.02 to 0.2) mol·kg<sup>−1</sup>.These measurements have been performed to evaluate some important parameters, viz, apparent molar volume of solute <span><math><mrow><mo>(</mo><msub><mi>V</mi><mi>ϕ</mi></msub><mo>)</mo></mrow></math></span>, limiting apparent molar volume of solute <span><math><mrow><mo>(</mo><msubsup><mi>V</mi><mi>ϕ</mi><mn>0</mn></msubsup><mo>)</mo></mrow></math></span>, limiting apparent molar volume of transfer <span><math><mrow><mo>(</mo><mrow><msub><mstyle><mi>Δ</mi></mstyle><mrow><mi>t</mi><mi>r</mi></mrow></msub><msubsup><mi>V</mi><mi>ϕ</mi><mn>0</mn></msubsup></mrow><mo>)</mo></mrow></math></span>, limiting apparent molar expansivity<span><math><mrow><mo>(</mo><msubsup><mi>E</mi><mi>ϕ</mi><mn>0</mn></msubsup><mo>)</mo></mrow></math></span>, thermal expansion coefficient (<span><math><msup><mi>α</mi><mo>*</mo></msup></math></span>), Hepler's constant <span><math><mrow><mo>(</mo><mfrac><mrow><msup><mi>∂</mi><mn>2</mn></msup><msubsup><mi>V</mi><mi>ϕ</mi><mn>0</mn></msubsup></mrow><mrow><mi>∂</mi><msup><mi>T</mi><mn>2</mn></msup></mrow></mfrac><mo>)</mo></mrow></math></span>, isentropic compressibility (<span><math><msub><mi>κ</mi><mi>s</mi></msub></math></span>), apparent molar compressibility <span><math><mrow><mo>(</mo><msub><mi>K</mi><mrow><mi>s</mi><mo>,</mo><mi>ϕ</mi></mrow></msub><mo>)</mo></mrow></math></span>, limiting apparent molar compressibility <span><math><mrow><mo>(</mo><msubsup><mi>K</mi><mrow><mi>s</mi><mo>,</mo><mi>ϕ</mi></mrow><mn>0</mn></msubsup><mo>)</mo></mrow></math></span>, limiting apparent molar isentropic compressibility of transfer <span><math><mrow><mo>(</mo><mrow><msub><mstyle><mi>Δ</mi></mstyle><mrow><mi>t</mi><mi>r</mi></mrow></msub><msubsup><mi>K</mi><mrow><mi>s</mi><mo>,</mo><mi>ϕ</mi></mrow><mn>0</mn></msubsup></mrow><mo>)</mo></mrow></math></span>and hydration number<span><math><mrow><mo>(</mo><msub><mi>η</mi><mi>H</mi></msub><mo>)</mo></mrow></math></span> . The results have been interpreted in terms of different interactions taking place in aqueous solutions.</p></div>","PeriodicalId":9781,"journal":{"name":"Chemical Thermodynamics and Thermal Analysis","volume":"7 ","pages":"Article 100061"},"PeriodicalIF":0.0000,"publicationDate":"2022-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S266731262200027X/pdfft?md5=b992da299a2f2138df21d018092c29ed&pid=1-s2.0-S266731262200027X-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Volumetric and acoustic studies of L-Citrulline in aqueous Urea and Dextrose solutions at different temperatures\",\"authors\":\"Nikhat G. Sheikh , Vijay M. Tangde , Niraj T. Khaty , Sudhakar S. Dhondge , Alka S. Dhondge\",\"doi\":\"10.1016/j.ctta.2022.100061\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Density <span><math><mrow><mo>(</mo><mi>ρ</mi><mo>)</mo></mrow></math></span> and speed of sound <span><math><mrow><mo>(</mo><mi>u</mi><mo>)</mo></mrow></math></span> values of L-Citrulline in aqueous solution, 0.06 mol·kg<sup>−1</sup> aqueous Urea and aqueous 0.06 mol·kg<sup>−1</sup> Dextrose solutions have been measured at <em>T</em> = (288.15, 293.15, 298.15, 303.15, 308.15, 313.15 and 318.15) K within the concentration range of (0.02 to 0.2) mol·kg<sup>−1</sup>.These measurements have been performed to evaluate some important parameters, viz, apparent molar volume of solute <span><math><mrow><mo>(</mo><msub><mi>V</mi><mi>ϕ</mi></msub><mo>)</mo></mrow></math></span>, limiting apparent molar volume of solute <span><math><mrow><mo>(</mo><msubsup><mi>V</mi><mi>ϕ</mi><mn>0</mn></msubsup><mo>)</mo></mrow></math></span>, limiting apparent molar volume of transfer <span><math><mrow><mo>(</mo><mrow><msub><mstyle><mi>Δ</mi></mstyle><mrow><mi>t</mi><mi>r</mi></mrow></msub><msubsup><mi>V</mi><mi>ϕ</mi><mn>0</mn></msubsup></mrow><mo>)</mo></mrow></math></span>, limiting apparent molar expansivity<span><math><mrow><mo>(</mo><msubsup><mi>E</mi><mi>ϕ</mi><mn>0</mn></msubsup><mo>)</mo></mrow></math></span>, thermal expansion coefficient (<span><math><msup><mi>α</mi><mo>*</mo></msup></math></span>), Hepler's constant <span><math><mrow><mo>(</mo><mfrac><mrow><msup><mi>∂</mi><mn>2</mn></msup><msubsup><mi>V</mi><mi>ϕ</mi><mn>0</mn></msubsup></mrow><mrow><mi>∂</mi><msup><mi>T</mi><mn>2</mn></msup></mrow></mfrac><mo>)</mo></mrow></math></span>, isentropic compressibility (<span><math><msub><mi>κ</mi><mi>s</mi></msub></math></span>), apparent molar compressibility <span><math><mrow><mo>(</mo><msub><mi>K</mi><mrow><mi>s</mi><mo>,</mo><mi>ϕ</mi></mrow></msub><mo>)</mo></mrow></math></span>, limiting apparent molar compressibility <span><math><mrow><mo>(</mo><msubsup><mi>K</mi><mrow><mi>s</mi><mo>,</mo><mi>ϕ</mi></mrow><mn>0</mn></msubsup><mo>)</mo></mrow></math></span>, limiting apparent molar isentropic compressibility of transfer <span><math><mrow><mo>(</mo><mrow><msub><mstyle><mi>Δ</mi></mstyle><mrow><mi>t</mi><mi>r</mi></mrow></msub><msubsup><mi>K</mi><mrow><mi>s</mi><mo>,</mo><mi>ϕ</mi></mrow><mn>0</mn></msubsup></mrow><mo>)</mo></mrow></math></span>and hydration number<span><math><mrow><mo>(</mo><msub><mi>η</mi><mi>H</mi></msub><mo>)</mo></mrow></math></span> . The results have been interpreted in terms of different interactions taking place in aqueous solutions.</p></div>\",\"PeriodicalId\":9781,\"journal\":{\"name\":\"Chemical Thermodynamics and Thermal Analysis\",\"volume\":\"7 \",\"pages\":\"Article 100061\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S266731262200027X/pdfft?md5=b992da299a2f2138df21d018092c29ed&pid=1-s2.0-S266731262200027X-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Thermodynamics and Thermal Analysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S266731262200027X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Thermodynamics and Thermal Analysis","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S266731262200027X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Volumetric and acoustic studies of L-Citrulline in aqueous Urea and Dextrose solutions at different temperatures
Density and speed of sound values of L-Citrulline in aqueous solution, 0.06 mol·kg−1 aqueous Urea and aqueous 0.06 mol·kg−1 Dextrose solutions have been measured at T = (288.15, 293.15, 298.15, 303.15, 308.15, 313.15 and 318.15) K within the concentration range of (0.02 to 0.2) mol·kg−1.These measurements have been performed to evaluate some important parameters, viz, apparent molar volume of solute , limiting apparent molar volume of solute , limiting apparent molar volume of transfer , limiting apparent molar expansivity, thermal expansion coefficient (), Hepler's constant , isentropic compressibility (), apparent molar compressibility , limiting apparent molar compressibility , limiting apparent molar isentropic compressibility of transfer and hydration number . The results have been interpreted in terms of different interactions taking place in aqueous solutions.