l -瓜氨酸在不同温度的尿素和葡萄糖水溶液中的体积和声学研究

Nikhat G. Sheikh , Vijay M. Tangde , Niraj T. Khaty , Sudhakar S. Dhondge , Alka S. Dhondge
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引用次数: 0

摘要

在T =(288.15、293.15、298.15、303.15、308.15、313.15和318.15)K时,在(0.02 ~ 0.2)mol·kg - 1浓度范围内,测定了l -瓜氨酸在水溶液、0.06 mol·kg - 1尿素水溶液和0.06 mol·kg - 1葡萄糖水溶液中的密度ρ和声速u值。这些测量已经被用来评估一些重要的参数,即溶质的表观摩尔体积(vφ),溶质的极限表观摩尔体积(Vϕ),极限表观摩尔转移体积(ΔtrVϕ0),极限表观摩尔膨胀率(Eϕ0),热膨胀系数(α*), Hepler常数(∂2Vϕ0∂T2),等熵可压缩性(κs),表观摩尔可压缩性(Ks,ϕ),极限表观摩尔可压缩性(Ks,ϕ),限制表观摩尔等熵传递压缩率(ΔtrKs,ϕ0)和水化数(ηH)。这些结果被解释为水溶液中发生的不同的相互作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Volumetric and acoustic studies of L-Citrulline in aqueous Urea and Dextrose solutions at different temperatures

Volumetric and acoustic studies of L-Citrulline in aqueous Urea and Dextrose solutions at different temperatures

Density (ρ) and speed of sound (u) values of L-Citrulline in aqueous solution, 0.06 mol·kg−1 aqueous Urea and aqueous 0.06 mol·kg−1 Dextrose solutions have been measured at T = (288.15, 293.15, 298.15, 303.15, 308.15, 313.15 and 318.15) K within the concentration range of (0.02 to 0.2) mol·kg−1.These measurements have been performed to evaluate some important parameters, viz, apparent molar volume of solute (Vϕ), limiting apparent molar volume of solute (Vϕ0), limiting apparent molar volume of transfer (ΔtrVϕ0), limiting apparent molar expansivity(Eϕ0), thermal expansion coefficient (α*), Hepler's constant (2Vϕ0T2), isentropic compressibility (κs), apparent molar compressibility (Ks,ϕ), limiting apparent molar compressibility (Ks,ϕ0), limiting apparent molar isentropic compressibility of transfer (ΔtrKs,ϕ0)and hydration number(ηH) . The results have been interpreted in terms of different interactions taking place in aqueous solutions.

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