{"title":"3-羟基-2-萘酰胺与氯-s-三嗪的反应","authors":"R. Budziarek, P. Hampson","doi":"10.1039/J39710001167","DOIUrl":null,"url":null,"abstract":"N.m.r., i.r. data, and chemical behaviour support the view that ionised 3-hydroxy-2-naphthanilide reacts with cyanuric chloride and with dichloro-s-triazines to form initially the O-s-triazinyl derivatives (3). These hydrolyse in acid to 3-hydroxy-2-naphthanilide; in the presence of alkali, however, O→N rearrangement of the s-triazine occurs to give the N-s-triazinyl derivatives (5) which hydrolyse to 3-hydroxy-2-naphthoic acid.","PeriodicalId":17245,"journal":{"name":"Journal of The Chemical Society C: Organic","volume":"10 1","pages":"1167-1170"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"The reaction of 3-hydroxy-2-naphthanilide with chloro-s-triazines\",\"authors\":\"R. Budziarek, P. Hampson\",\"doi\":\"10.1039/J39710001167\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"N.m.r., i.r. data, and chemical behaviour support the view that ionised 3-hydroxy-2-naphthanilide reacts with cyanuric chloride and with dichloro-s-triazines to form initially the O-s-triazinyl derivatives (3). These hydrolyse in acid to 3-hydroxy-2-naphthanilide; in the presence of alkali, however, O→N rearrangement of the s-triazine occurs to give the N-s-triazinyl derivatives (5) which hydrolyse to 3-hydroxy-2-naphthoic acid.\",\"PeriodicalId\":17245,\"journal\":{\"name\":\"Journal of The Chemical Society C: Organic\",\"volume\":\"10 1\",\"pages\":\"1167-1170\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society C: Organic\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J39710001167\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society C: Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J39710001167","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The reaction of 3-hydroxy-2-naphthanilide with chloro-s-triazines
N.m.r., i.r. data, and chemical behaviour support the view that ionised 3-hydroxy-2-naphthanilide reacts with cyanuric chloride and with dichloro-s-triazines to form initially the O-s-triazinyl derivatives (3). These hydrolyse in acid to 3-hydroxy-2-naphthanilide; in the presence of alkali, however, O→N rearrangement of the s-triazine occurs to give the N-s-triazinyl derivatives (5) which hydrolyse to 3-hydroxy-2-naphthoic acid.
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