提高芳纶/环氧复合材料力学性能的方法研究

A. Yermakhanova, B.M. Baiserikov, A. Kenzhegulov, M. Meiirbekov, Bauyrzhan Yerbolsynuly Zhumadilov
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引用次数: 0

摘要

高分子复合材料,特别是芳纶-环氧复合材料,由于其优异的力学性能和介电性能,在航空航天、交通运输、电子等领域得到了广泛的应用。本文介绍了改性和复合增强对芳纶-环氧复合材料力学性能的影响。研究了基体(环氧树脂)和补强填料(芳纶织物)质量比对复合材料强度特性和冲击韧性的影响以及提高复合材料强度特性和冲击韧性的途径。对真空成形法和真空灌注法制备的复合材料进行了对比研究。补强填料与基体的质量比分别为50:50%、60:40%、65:35%、75:25%。结果表明,用聚氨酯橡胶增塑剂改性环氧树脂,结合芳纶织物/芳纶粗纱的复合增强,复合强度可达720 MPa,冲击韧性达426 kJ/m2。用磷酸三甲酯改性环氧树脂,复合强度可达710 MPa,冲击韧性为475 kJ/m2。由此可见,对芳纶-环氧复合材料进行改性和复合增强是提高其强度和与环氧树脂结合力的最有效方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study on methods to improve the mechanical properties of aramid/epoxy composites
Polymer composites, in particular aramid-epoxy composites, are widely used in fields such as aerospace, transportation, electronics, etc. due to their excellent mechanical and dielectric properties. This article presents studies of modification and combined reinforcement on the mechanical properties of aramid-epoxy composites. The influence of matrix (epoxy resin) and reinforcing filler (aramid fabric) mass ratio and ways to increase strength characteristics and impact toughness of the composite were studied. Comparative results for composites made by vacuum forming and vacuum infusion methods are presented. Mass ratio of reinforcing filler and matrix varied in the range of 50:50%, 60:40%, 65:35%, and 75:25%. It was found that modifying epoxy resin with polyurethane rubber plasticizer, together with combined reinforcement of aramid fabric/aramid roving, resulted in composite strength up to 720 MPa and impact toughness of 426 kJ/m2. Modification of epoxy resin with tricresyl phosphate leads to composite strength up to 710 MPa and impact toughness of 475 kJ/m2. Thus, it is shown that modification and combined reinforcement of aramid-epoxy composites are the most effective methods to increase strength and adhesion to epoxy resin.
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