新型anderson型多金属氧酸盐的合成与表征:[M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]·16H2O (M=Cr, Mn, Co, Ni, Cu)x = 1, 2)

Journal of the Turkish Chemical Society Section A: Chemistry Pub Date : 2023-04-14 DOI:10.18596/jotcsa.1215066

Hülya Avcı Özbek

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引用次数: 0

摘要

五种新型anderson型多金属氧酸化合物[M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]∙16H2O (M=Cr(1)， Mn(2)， Co(3)， Ni(4)， Cu(5));x=1,2)分别由Na2MoO4∙2H2O和CrCl3∙6H2O在酸性水介质(pH=2-3)中得到。通过FT-IR、TGA、ICP-MS和元素分析等手段对化合物进行了表征。结构分析表明化合物(1 ~ 5)由anderson型聚阴离子[Cr(OH)6Mo6O18]3-组成。

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Synthesis and Characterization of New Anderson-Type Polyoxometalates: [M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]·16H2O (M=Cr, Mn, Co, Ni, Cu; x=1,2)

Five new Anderson-type polyoxometalate compounds [M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]∙16H2O (M=Cr(1), Mn(2), Co(3), Ni(4), Cu(5); x=1,2) were obtained from Na2MoO4∙2H2O and CrCl3∙6H2O within acidic aqueous medium (pH=2-3). The compounds are characterized by means of FT-IR, TGA, ICP-MS, and elemental analysis techniques. The structural analysis show that compounds (1-5) consist of a Anderson-type polyanion [Cr(OH)6Mo6O18]3-.

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Journal of the Turkish Chemical Society Section A: Chemistry

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