用纠缠轨迹分子动力学方法研究多色微扰双阱系统的量子动力学

Feng Xu, Lei Zhang, Yujun Zheng
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引用次数: 1

摘要

本文用纠缠轨迹分子动力学方法研究了频率不匹配的随时间扰动的双阱系统的量子动力学。首先比较了经典动力学下两模摄动驱动系统与量子动力学下一模摄动驱动系统的能量时间演化,发现量子动力学符合Ehrenfest定理,证明了用纠缠轨迹分子动力学方法得到的结果是正确和准确的。量子相干性抑制初始能量高于势垒的轨迹,这一过程被称为隧穿的相干破坏(CDT)。我们通过在相空间中展示纠缠轨迹和相应的经典轨迹来证明这一有趣的现象,并讨论了它们的能量随时间的涨落。此外,我们从自相关演化的角度讨论了不同频模扰动下的量子动力学,经典混沌对量子力学现象的影响是显著的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Quantum dynamics in double-well system with polychromatic perturbation using entangled trajectory molecular dynamics method
We investigate quantum dynamics in a double-well system subject to time- dependent perturbation with some incommensurate frequencies using entangled tra- jectory molecular dynamics method. We first compare time evolution of energy of the driven system with two mode perturbation under classical dynamics with one under quantum dynamics, it is found that quantum dynamics obeys Ehrenfest's theorem and it shows our results obtain from entangled trajectory molecular dynamics method are correct and accurate. Quantum coherence suppresses trajectory which initial energy is higher than barrier to get over it, this process is named coherent destruction of tun- neling (CDT). We show this interesting phenomenon through showing entangled tra- jectory and corresponding classical trajectory in phase space and discuss their energy fluctuation with time. Furthermore, we discuss quantum dynamics with different fre- quency mode perturbation from the perspective of autocorrelation evolution, classical chaos brings remarkable influence on quantum-mechanical phenomena.
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来源期刊
Journal of Atomic and Molecular Sciences
Journal of Atomic and Molecular Sciences PHYSICS, ATOMIC, MOLECULAR & CHEMICAL-
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