一些多氯有机化合物的正离子质谱

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI:10.1039/J19710000632

S. C. Cohen

{"title":"一些多氯有机化合物的正离子质谱","authors":"S. C. Cohen","doi":"10.1039/J19710000632","DOIUrl":null,"url":null,"abstract":"The mass spectra of bis(pentachlorophenyl)mercury, pentachlorophenylmercury(II) chloride, bis(trichlorovinyl)-mercury, and trichlorovinylmercury(II) chloride yield (R – Cl)+ as the most intense organo-ion. This is explained, by use of clastograms and relative appearance potentials, as being due to the preferential elimination of HgCl2 rather than Hg–C bond cleavage, RHgX+ [graphic omitted] RHg+ [graphic omitted] R+(X = R or Cl).","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":"54 4","pages":"632-636"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Positive-ion mass spectra of some polychloro-organomercurials\",\"authors\":\"S. C. Cohen\",\"doi\":\"10.1039/J19710000632\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The mass spectra of bis(pentachlorophenyl)mercury, pentachlorophenylmercury(II) chloride, bis(trichlorovinyl)-mercury, and trichlorovinylmercury(II) chloride yield (R – Cl)+ as the most intense organo-ion. This is explained, by use of clastograms and relative appearance potentials, as being due to the preferential elimination of HgCl2 rather than Hg–C bond cleavage, RHgX+ [graphic omitted] RHg+ [graphic omitted] R+(X = R or Cl).\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":\"54 4\",\"pages\":\"632-636\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710000632\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710000632","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 4

摘要

质谱中二(五氯苯基)汞、五氯苯基氯化汞、二(三氯苯基)汞和三氯苯基氯化汞的产率(R - Cl)+为最强烈的有机离子。通过使用破片图和相对外观电位，可以解释这是由于HgCl2优先消除而不是Hg-C键解理，RHgX+[图略]RHg+[图略]R+(X = R或Cl)。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Positive-ion mass spectra of some polychloro-organomercurials

The mass spectra of bis(pentachlorophenyl)mercury, pentachlorophenylmercury(II) chloride, bis(trichlorovinyl)-mercury, and trichlorovinylmercury(II) chloride yield (R – Cl)+ as the most intense organo-ion. This is explained, by use of clastograms and relative appearance potentials, as being due to the preferential elimination of HgCl2 rather than Hg–C bond cleavage, RHgX+ [graphic omitted] RHg+ [graphic omitted] R+(X = R or Cl).

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of The Chemical Society A: Inorganic, Physical, Theoretical

自引率

0.00%

发文量