阶梯型聚(3,4-乙烯二氧噻吩)-聚(乙二醇)-聚氨酯凝胶聚合物电解质超分子网络

Q2 Materials Science

Polymer-Plastics Technology and Engineering Pub Date : 2018-08-13 DOI:10.1080/03602559.2017.1381238

C. Jee, K. Kang, J. Bae, H. Jung, H. Park, J. Yang, P. Huh

{"title":"阶梯型聚(3,4-乙烯二氧噻吩)-聚(乙二醇)-聚氨酯凝胶聚合物电解质超分子网络","authors":"C. Jee, K. Kang, J. Bae, H. Jung, H. Park, J. Yang, P. Huh","doi":"10.1080/03602559.2017.1381238","DOIUrl":null,"url":null,"abstract":"ABSTRACT A ladder-type poly(3,4-ethylenedioxythiophene)-poly (ethylene glycol)-polyurethane (PEDOT-PEG-PU) supramolecular network was successfully synthesized using graft copolymerization of hydroxymethyl-EDOT with isocyanate-terminated PEG-PU prepolymer. PEDOT functionalized as the frame for a ladder-type supramolecular structure and PEG-PU as the rung. The successful formation of supramolecular network was confirmed by analyzing the Fourier transform infrared spectroscopy (FTIR). A series of PEDOT-PEG-PU gel polymer electrolyte by linking the LiClO4 were prepared as a function of [O/Li+] ratios. The pH effect of their electrical capacitances was investigated using cyclic voltammetry. Ionic conductivities of different PEDOT-PEG-PU/Li+ complexes at a fixed pH were also evaluated through impedance analysis. GRAPHICAL ABSTRACT","PeriodicalId":20629,"journal":{"name":"Polymer-Plastics Technology and Engineering","volume":"1202 ","pages":"1236 - 1241"},"PeriodicalIF":0.0000,"publicationDate":"2018-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1080/03602559.2017.1381238","citationCount":"1","resultStr":"{\"title\":\"Ladder-Type Poly(3,4-ethylenedioxythiophene)-Poly (ethylene glycol)-Polyurethane Supramolecular Network for Gel Polymer Electrolyte\",\"authors\":\"C. Jee, K. Kang, J. Bae, H. Jung, H. Park, J. Yang, P. Huh\",\"doi\":\"10.1080/03602559.2017.1381238\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT A ladder-type poly(3,4-ethylenedioxythiophene)-poly (ethylene glycol)-polyurethane (PEDOT-PEG-PU) supramolecular network was successfully synthesized using graft copolymerization of hydroxymethyl-EDOT with isocyanate-terminated PEG-PU prepolymer. PEDOT functionalized as the frame for a ladder-type supramolecular structure and PEG-PU as the rung. The successful formation of supramolecular network was confirmed by analyzing the Fourier transform infrared spectroscopy (FTIR). A series of PEDOT-PEG-PU gel polymer electrolyte by linking the LiClO4 were prepared as a function of [O/Li+] ratios. The pH effect of their electrical capacitances was investigated using cyclic voltammetry. Ionic conductivities of different PEDOT-PEG-PU/Li+ complexes at a fixed pH were also evaluated through impedance analysis. GRAPHICAL ABSTRACT\",\"PeriodicalId\":20629,\"journal\":{\"name\":\"Polymer-Plastics Technology and Engineering\",\"volume\":\"1202 \",\"pages\":\"1236 - 1241\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-08-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1080/03602559.2017.1381238\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer-Plastics Technology and Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/03602559.2017.1381238\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Materials Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer-Plastics Technology and Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/03602559.2017.1381238","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Materials Science","Score":null,"Total":0}

引用次数: 1

摘要

摘要以羟基甲基- edot与端部异氰酸酯的PEG-PU预聚物接枝共聚，成功合成了阶梯型聚(3,4-乙烯二氧噻吩)-聚乙二醇-聚氨酯(PEDOT-PEG-PU)超分子网络。PEDOT功能化为阶梯型超分子结构的框架，PEG-PU功能化为梯级。通过傅里叶红外光谱(FTIR)分析证实了超分子网络的成功形成。通过连接LiClO4制备了一系列以[O/Li+]比值为函数的PEDOT-PEG-PU凝胶聚合物电解质。用循环伏安法研究了它们的电容量对pH的影响。通过阻抗分析，评价了固定pH下不同PEDOT-PEG-PU/Li+配合物的离子电导率。图形抽象

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Ladder-Type Poly(3,4-ethylenedioxythiophene)-Poly (ethylene glycol)-Polyurethane Supramolecular Network for Gel Polymer Electrolyte

ABSTRACT A ladder-type poly(3,4-ethylenedioxythiophene)-poly (ethylene glycol)-polyurethane (PEDOT-PEG-PU) supramolecular network was successfully synthesized using graft copolymerization of hydroxymethyl-EDOT with isocyanate-terminated PEG-PU prepolymer. PEDOT functionalized as the frame for a ladder-type supramolecular structure and PEG-PU as the rung. The successful formation of supramolecular network was confirmed by analyzing the Fourier transform infrared spectroscopy (FTIR). A series of PEDOT-PEG-PU gel polymer electrolyte by linking the LiClO4 were prepared as a function of [O/Li+] ratios. The pH effect of their electrical capacitances was investigated using cyclic voltammetry. Ionic conductivities of different PEDOT-PEG-PU/Li+ complexes at a fixed pH were also evaluated through impedance analysis. GRAPHICAL ABSTRACT

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Polymer-Plastics Technology and Engineering 工程技术-高分子科学

CiteScore

1.71

自引率

0.00%

发文量

审稿时长

4 months