{"title":"氢键合高铼酸偶氮咪唑","authors":"U.S. Ray , G. Mostafa , T.H. Lu , C. Sinha","doi":"10.1016/S1463-0184(02)00013-8","DOIUrl":null,"url":null,"abstract":"<div><p>Reaction in aqueous medium of KReO<sub>4</sub> in methanolic solution of RaaiCH<sub>2</sub>Ph (1-benzyl-2-(arylazo)imidazole) (<strong>1</strong><span>) in the presence of perchloric acid has isolated brown products of {[1-benzyl-2-(arylazo)imidazolium][ReO</span><sub>4</sub><sup>−</sup>]<img>H<sub>2</sub>O}<em><sub>n</sub></em>, <strong>2</strong>. The structural confirmation has been carried out by the single crystal X-ray diffraction study of {[1-benzyl-2-(phenylazo)imidazolium][ReO<sub>4</sub><sup>−</sup>]<img>H<sub>2</sub>O}, <strong>2a</strong>. The molecules are polymerized via hydrogen bonding and form cross-linked network.</p></div>","PeriodicalId":10766,"journal":{"name":"Crystal Engineering","volume":"5 2","pages":"Pages 95-104"},"PeriodicalIF":0.0000,"publicationDate":"2002-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1463-0184(02)00013-8","citationCount":"14","resultStr":"{\"title\":\"Hydrogen bonded perrhenate-azoimidazoles\",\"authors\":\"U.S. Ray , G. Mostafa , T.H. Lu , C. Sinha\",\"doi\":\"10.1016/S1463-0184(02)00013-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Reaction in aqueous medium of KReO<sub>4</sub> in methanolic solution of RaaiCH<sub>2</sub>Ph (1-benzyl-2-(arylazo)imidazole) (<strong>1</strong><span>) in the presence of perchloric acid has isolated brown products of {[1-benzyl-2-(arylazo)imidazolium][ReO</span><sub>4</sub><sup>−</sup>]<img>H<sub>2</sub>O}<em><sub>n</sub></em>, <strong>2</strong>. The structural confirmation has been carried out by the single crystal X-ray diffraction study of {[1-benzyl-2-(phenylazo)imidazolium][ReO<sub>4</sub><sup>−</sup>]<img>H<sub>2</sub>O}, <strong>2a</strong>. The molecules are polymerized via hydrogen bonding and form cross-linked network.</p></div>\",\"PeriodicalId\":10766,\"journal\":{\"name\":\"Crystal Engineering\",\"volume\":\"5 2\",\"pages\":\"Pages 95-104\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1463-0184(02)00013-8\",\"citationCount\":\"14\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Crystal Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1463018402000138\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1463018402000138","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Reaction in aqueous medium of KReO4 in methanolic solution of RaaiCH2Ph (1-benzyl-2-(arylazo)imidazole) (1) in the presence of perchloric acid has isolated brown products of {[1-benzyl-2-(arylazo)imidazolium][ReO4−]H2O}n, 2. The structural confirmation has been carried out by the single crystal X-ray diffraction study of {[1-benzyl-2-(phenylazo)imidazolium][ReO4−]H2O}, 2a. The molecules are polymerized via hydrogen bonding and form cross-linked network.
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