Yurii A Simonov , Marina S Fonari , Janusz Lipkowski , Edward V Ganin , Arkadii A Yavolovskii
{"title":"18-冠-6与芳香族氨基硫脲衍生物共晶体中的层和链结构","authors":"Yurii A Simonov , Marina S Fonari , Janusz Lipkowski , Edward V Ganin , Arkadii A Yavolovskii","doi":"10.1016/S1472-7862(03)00051-0","DOIUrl":null,"url":null,"abstract":"<div><p>The crystal structures of 1:2 binary complexes of 18-crown-6 with two thiosemicarbazide derivatives, phenylthiosemicarbazide (<strong>PH</strong>), (<strong>1</strong>) and quinoline thiosemicarbazide (<strong>QH</strong>), (<strong>2</strong>) are reported. Compound <strong>1</strong> displays a layered structure formed by the association of <strong>PH</strong> zigzag chains and crown molecules. In compound <strong>2</strong> centrosymmetric <strong>QH</strong> dimers alternate with the crown spacers in the chains. Both structures are sustained by N–H<sup>…</sup>O and N–H<sup>…</sup><span>S hydrogen bonds.</span></p></div>","PeriodicalId":100833,"journal":{"name":"Journal of Supramolecular Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2002-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1472-7862(03)00051-0","citationCount":"4","resultStr":"{\"title\":\"Layer and chain structures in the co-Crystals of 18-Crown-6 with aromatic thiosemicarbazide derivatives\",\"authors\":\"Yurii A Simonov , Marina S Fonari , Janusz Lipkowski , Edward V Ganin , Arkadii A Yavolovskii\",\"doi\":\"10.1016/S1472-7862(03)00051-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The crystal structures of 1:2 binary complexes of 18-crown-6 with two thiosemicarbazide derivatives, phenylthiosemicarbazide (<strong>PH</strong>), (<strong>1</strong>) and quinoline thiosemicarbazide (<strong>QH</strong>), (<strong>2</strong>) are reported. Compound <strong>1</strong> displays a layered structure formed by the association of <strong>PH</strong> zigzag chains and crown molecules. In compound <strong>2</strong> centrosymmetric <strong>QH</strong> dimers alternate with the crown spacers in the chains. Both structures are sustained by N–H<sup>…</sup>O and N–H<sup>…</sup><span>S hydrogen bonds.</span></p></div>\",\"PeriodicalId\":100833,\"journal\":{\"name\":\"Journal of Supramolecular Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1472-7862(03)00051-0\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Supramolecular Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1472786203000510\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Supramolecular Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1472786203000510","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Layer and chain structures in the co-Crystals of 18-Crown-6 with aromatic thiosemicarbazide derivatives
The crystal structures of 1:2 binary complexes of 18-crown-6 with two thiosemicarbazide derivatives, phenylthiosemicarbazide (PH), (1) and quinoline thiosemicarbazide (QH), (2) are reported. Compound 1 displays a layered structure formed by the association of PH zigzag chains and crown molecules. In compound 2 centrosymmetric QH dimers alternate with the crown spacers in the chains. Both structures are sustained by N–H…O and N–H…S hydrogen bonds.
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