氯化二喹啉主体的包合性质

A.Noman M.M. Rahman, Roger Bishop, Donald C. Craig, Marcia L. Scudder
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引用次数: 6

摘要

制备了新的晶格包裹体6α,13α-二溴-2,9-二氯-5bα,6,12bα,13四氢戊并[1,2-b:4,5-b′]二喹啉8,发现其包含的客体远少于其非氯化类似物2。化合物(8)2·(乙酸乙酯)和(8)2.(苯)分别形成分子笔和阶梯包合物。从晶体工程的角度对它们的X射线结构进行了分析和比较。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Inclusion Properties of a Chlorinated Diquinoline Host

The new lattice inclusion host 6α,13α-dibromo-2,9-dichloro-5bα,6,12bα,13-tetrahydropentaleno[1,2-b:4,5-b′]diquinoline 8 was prepared, and found to include far fewer guests than its non-chlorinated analogue 2. Compounds (8)2·(ethyl acetate) and (8)2·(benzene) form molecular pen and staircase inclusion compounds respectively. Their X-ray structures are analysed and compared in crystal engineering terms.

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