使用可回收螯合树脂从水溶液中选择性识别和提取铀酰离子†

IF 7.6 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chemical Science Pub Date : 2013-07-01 DOI:10.1039/C3SC51507A

Aaron C. Sather, Orion B. Berryman and Julius Rebek

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引用次数: 0

摘要

制备了一种离子交换聚合物1，该聚合物结合了针对铀酰离子设计的螯合配体，并研究了其从水溶液中去除铀的能力。螯合模块显示形成1 : 1和溶液中的铀酰离子的络合物。在铀酰提取实验中进行了1与标准亚氨基二乙酸螯合树脂Chelex 100的比较。1有效地从水溶液中提取铀酰离子，包括掺入的海水，并可完全回收至少15个提取循环。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Selective recognition and extraction of the uranyl ion from aqueous solutions with a recyclable chelating resin†

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Selective recognition and extraction of the uranyl ion from aqueous solutions with a recyclable chelating resin†

An ion exchange polymer 1, incorporating a chelating ligand engineered for the uranyl ion was prepared and its ability to remove uranium from aqueous solutions was studied. The chelating module was shown to form a 1 : 1 complex with the uranyl ion in solution. Comparisons of 1 with the standard imidodiacetate chelating resin, Chelex 100 were performed in uranyl extraction experiments. 1 effectively extracts uranyl ion from aqueous solutions, including spiked seawater, and is fully recyclable for at least 15 extraction cycles.

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来源期刊

Chemical Science CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

14.40

自引率

4.80%

发文量

1352

审稿时长

2.1 months

期刊介绍： Chemical Science is a journal that encompasses various disciplines within the chemical sciences. Its scope includes publishing ground-breaking research with significant implications for its respective field, as well as appealing to a wider audience in related areas. To be considered for publication, articles must showcase innovative and original advances in their field of study and be presented in a manner that is understandable to scientists from diverse backgrounds. However, the journal generally does not publish highly specialized research.