{"title":"UOs2和UOsIr的比热","authors":"M Baldus, B Andraka, G.R Stewart","doi":"10.1016/0022-5088(91)90002-L","DOIUrl":null,"url":null,"abstract":"<div><p>The low temperature specific heats of C-15 structure UOs<sub>2</sub> and UOsIR have been measured in order to compare them with the systems NpOs<sub>2</sub>, a ferromagnet with <em>T</em><sub><em>Curie</em> = 7.9 K</sub>, and NpOsIr, newly discovered to be a spin fluctuation system with a specific heat γ of 375 mJ mol<sup>−1</sup> K<sup>−2</sup>. The uranium compounds, with U—U separations of 3.25 Å, less than the Hill limit of 3.4 Å, show normal metallic behavior, with <em>γ</em>(<em>UOs</em><sub>2</sub>) = 20 ± 2 mJ mol<sup>−1</sup><em>K</em><sup>−2</sup> and <em>γ</em>(<em>UOsIr</em>) = 33 ± 3 mJ mol<sup>−1</sup> K<sup>−2</sup>.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 2","pages":"Pages L11-L13"},"PeriodicalIF":0.0000,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90002-L","citationCount":"0","resultStr":"{\"title\":\"Specific Heat of UOs2 and UOsIr\",\"authors\":\"M Baldus, B Andraka, G.R Stewart\",\"doi\":\"10.1016/0022-5088(91)90002-L\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The low temperature specific heats of C-15 structure UOs<sub>2</sub> and UOsIR have been measured in order to compare them with the systems NpOs<sub>2</sub>, a ferromagnet with <em>T</em><sub><em>Curie</em> = 7.9 K</sub>, and NpOsIr, newly discovered to be a spin fluctuation system with a specific heat γ of 375 mJ mol<sup>−1</sup> K<sup>−2</sup>. The uranium compounds, with U—U separations of 3.25 Å, less than the Hill limit of 3.4 Å, show normal metallic behavior, with <em>γ</em>(<em>UOs</em><sub>2</sub>) = 20 ± 2 mJ mol<sup>−1</sup><em>K</em><sup>−2</sup> and <em>γ</em>(<em>UOsIr</em>) = 33 ± 3 mJ mol<sup>−1</sup> K<sup>−2</sup>.</p></div>\",\"PeriodicalId\":17534,\"journal\":{\"name\":\"Journal of The Less Common Metals\",\"volume\":\"175 2\",\"pages\":\"Pages L11-L13\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1991-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-5088(91)90002-L\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Less Common Metals\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/002250889190002L\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Less Common Metals","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/002250889190002L","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The low temperature specific heats of C-15 structure UOs2 and UOsIR have been measured in order to compare them with the systems NpOs2, a ferromagnet with TCurie = 7.9 K, and NpOsIr, newly discovered to be a spin fluctuation system with a specific heat γ of 375 mJ mol−1 K−2. The uranium compounds, with U—U separations of 3.25 Å, less than the Hill limit of 3.4 Å, show normal metallic behavior, with γ(UOs2) = 20 ± 2 mJ mol−1K−2 and γ(UOsIr) = 33 ± 3 mJ mol−1 K−2.