任意解离程度下h2x型气体分子(X = O或S)中组分的a(H)和a(X)化学活性

IF 0.7 4区 管理学 Q3 COMMUNICATION
N. Shohoji
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引用次数: 3

摘要

采用由Katsura开发的热力学分析方法,以温度T和解离程度α为函数来评价H2X型气体分子(X = S或O)中组分X和H的化学活性a(X)和a(H),该方法用于解释流动抑制α的NH3气体分子中a(N)和a(H)的增强。目前的分析结果表明,H2S和H2O气体分子即使在相对较低的α下也具有相当的化学惰性,这与氮族三氢化物XH3不同,后者被证明在远离热力学平衡的状态下每种组分都具有很高的化学活性。表征HnX型气体分子解离程度的参数α是评价未解离的HnX气体分子中a(X)和a(H)化学活性的重要参数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Chemical Activities, a(H) and a(X), of Constituents in H 2 X Type Gas Molecules (X = O or S) at Arbitrary Degree of Dissociation
Chemical activities, a(X) and a(H), of constituents, X and H, in H2X type gas molecules (X = S or O) were evaluated as functions of temperature T and extent α of dissociation adapting a thermodynamic analysis procedure developed by Katsura for interpreting enhanced a(N) and a(H) in NH3 gas molecules with suppressed α by flowing. Present analysis results showed that both H2S and H2O gas molecules are chemically rather inert even at comparatively low α unlike nitro- gen-family tri-hydrides XH3 that were proved to yield high chemical activity of each constituent in a state being away from thermodynamic equilibrium. The parameter α referring to the extent of dissociation of HnX type gas molecules appears to be a significant parameter in evaluating the chemical activities, a(X) and a(H), in the HnX gas molecules that are remained non-dissociated.
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来源期刊
自引率
12.50%
发文量
66
期刊介绍: The world of mobile communications is not a trend, but a phenomenon. IJMC, a fully refereed journal, publishes articles that present current practice and theory of mobile communications, mobile technology, and mobile commerce applications. Topics covered include Integrated mobile marketing communications Wireless advertising/CRM Telematics, pervasive computing Incoming/outgoing wireless links Location management Diffusion, security, efficacy, interaction/integration Metric mobile business enterprises PDAs in services delivery M-/u-business models, m-/u-commerce Digital office, groupware, roomware Mobile ad hoc networking, wireless information assurance Nomadic/portable communications Cross-cultural mobile communications Teaching mobile communication applications Mobile/handheld devices in the classroom, tele-learning.
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