部分封闭电极上不可逆电氧化的模拟

IF 1.1 Q4 ELECTROCHEMISTRY

Portugaliae Electrochimica Acta Pub Date : 2020-01-01 DOI:10.4152/pea.202003165

M. Lovrić, Š. Komorsky-Lovrić

引用次数: 2

摘要

从理论上分析了可逆电位依赖性抑制对不可逆电极反应的影响。在循环伏安法中，电极表面再活化的结果是电氧化的继续和第二个阳极峰的出现。提出了一种表征缓蚀剂引起的电极动力学变化的指标。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode

An irreversible electrode reaction influenced by the reversible potential dependent inhibition is theoretically analysed. The consequence of reactivation of the electrode surface is the continuation of electro-oxidation and the appearance of the second anodic peak in cyclic voltammetry. An indicator of the change of the electrode kinetics caused by the inhibitor is proposed.

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来源期刊

Portugaliae Electrochimica Acta ELECTROCHEMISTRY-

CiteScore

2.30

自引率

16.70%

发文量

期刊介绍： Portugaliae Electrochimica Acta is a bi-monthly Journal published by the Portuguese Electrochemical Society since 1983. Portugaliae Electrochimica Acta publishes original papers, brief communications, reviews and letters concerned with every aspect of theory and practice of electrochemistry, as well as articles in which topics on history, science policy, education, etc. in the electrochemical field (teaching or research) may be discussed.