Ba取代对bifeo3结构和磁性能的影响

V. Srinivas, A. Raghavender, K. Kumar
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引用次数: 8

摘要

采用溶胶-凝胶法制备了Bi1-xBaxFeO3(0≤x≤0.3)纳米粉体。利用x射线衍射、扫描电镜和VSM对其结构和磁性能进行了表征。随着Ba2+掺杂浓度的增加,样品的结构由菱面体变为四方或单斜体。结构变化可能是实现该材料铁电性能的重要因素。晶格参数随Ba2+浓度的增加而增加。所有的M-H环都表现出铁磁性。磁化强度随Ba浓度的增加而增强。由于Ba2+掺杂导致的磁化强度增强可能是由于Ba2+取代了Bi3+离子,从而抑制了螺旋自旋结构。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Ba Substitution on the Structural and Magnetic Properties of BiFeO 3
Bi1-xBaxFeO3 (0 ≤ x ≤ 0.3) nanopowders were synthesized using sol-gel technique. The structural and magnetic properties were investigated using X-ray diffraction, SEM and VSM. As Ba2+ doping concentration was increased, the structure of the samples changed from rhombohedral to tetragonal or monoclinic. The structural change might be an important factor for achieving the ferroelectric properties in this material. The lattice parameters were observed to increase with increase in Ba2+ concentration. All the M-H loops showed the ferromagnetic behavior. Magnetization was observed to enhance with increase in Ba concentration. The enhancement in the magnetization due to Ba2+ doping may be due to the replacement of Bi3+ ions by Ba2+ which might have resulted in the suppression of spiral spin structure.
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