一锅法合成Cu, Mn基金属卟啉的收率优化

IF 0.6 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Journal of the chemical society of pakistan Pub Date : 2022-01-01 DOI:10.52568/001119/jcsp/44.05.2022

Saad Nadeem Saad Nadeem, Fahim Uddin Fahim Uddin, Maizatul Shima Shaharun Maizatul Shima Shaharun, Mohamed Ibrahim Abdul Mutalib Mohamed Ibrahim Abdul Mutalib

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引用次数: 0

摘要

以Cu基和Mn基四苯基卟啉cuppp和MnTPP为原料，采用一锅法合成cuppp和MnTPP，并根据目标大环配体合成过程中的能量消耗优化了反应条件(温度和时间)。采用温度(145℃、160℃)和时间(3、4、8小时)对产物收率的影响进行了研究。利用MATLAB例程得到的优化值为3.7小时，温度145℃。

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Yield Optimization for One Pot Synthesis of Cu, Mn based Metalloporphyrin

Cu and Mn based tetraphenyl porphyrin namely CuTPP and MnTPP were synthesized through a one pot route with a modified procedure and the reaction conditions (Temperature and time) were optimized based on the energy consumption during the synthesis of the target macrocyclic ligands. The temperature (145oC and 160oC) and time (3, 4, 8 hr) were used to study the effect on the product yield. The optimized values obtained using MATLAB routines are 3.7 hr and 145oC.

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来源期刊

Journal of the chemical society of pakistan 化学-化学综合

CiteScore

1.30

自引率

14.30%

发文量

审稿时长

3.4 months

期刊介绍： This journal covers different research areas in the field of Chemistry. These include; Analytical Chemistry, Applied Chemistry, Biochemistry, Environmental Chemistry, Industrial Chemistry, Inorganic Chemistry, Organic Chemistry and Physical Chemistry. The journal publishes full length articles and Reviews from researchers in academia in addition to featuring comments. Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry.