富勒烯与4-苯并-9-冠-3醚的功能化

IF 0.5 4区工程技术 Q4 CHEMISTRY, APPLIED

Indian Journal of Chemical Technology Pub Date : 2023-01-01 DOI:10.56042/ijct.v30i1.64953

K. Maryam, Mouji Hamid, Eskandari Hossein

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引用次数: 0

摘要

:هلاقم هصلاخ通过۴-benzo-۹-crown-۳ether重氮盐的共价加成，描述了富勒烯的功能化。冠醚的共价接枝使得富勒烯在有机溶剂和水生溶剂(如乙醇、二甲亚砜、二甲基甲酰胺和水)中的溶解度显著提高。在二氯甲烷、丙酮和乙醇中溶解度最高。共价键合的۴-benzo-۹-crown- ether允许fli +的托管。用红外光谱、紫外/可见光谱和热重分析等方法鉴定并证实了冠醚与富勒烯的共价接枝。

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Functionalization of fullerene with 4-benzo-9-crown-3 ether

:هلاقم هصلاخ Functionalization ofFullerene by the covalent addition of ۴-benzo-۹-crown-۳ether diazonium salt has beendescribed. The covalent grafting ofcrown etherhas led to a considerable increase in the solubility ofFullerene in both organicand aquatic solvents such as ethanol, dimethylsulfoxide, dimethylformamideand water. The highest solubilitywas attained in Dichloromethane, Acetone andEthanol. The covalently bonded ۴-benzo-۹-crown-۳ ether allowed the hosting ofLi+. The covalentgrafting of crown ether [۴-(benzo-۹-crown-۳)] to Fullerenewasidentified and confirmed by infrared spectroscopy, UV/Vis andthermogravimetric analysismethods.

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来源期刊

Indian Journal of Chemical Technology 工程技术-工程：化工

CiteScore

0.90

自引率

20.00%

发文量

审稿时长

6-12 weeks

期刊介绍： Indian Journal of Chemical Technology has established itself as the leading journal in the exciting field of chemical engineering and technology. It is intended for rapid communication of knowledge and experience to engineers and scientists working in the area of research development or practical application of chemical technology. This bimonthly journal includes novel and original research findings as well as reviews in the areas related to – Chemical Engineering, Catalysis, Leather Processing, Polymerization, Membrane Separation, Pharmaceuticals and Drugs, Agrochemicals, Reaction Engineering, Biochemical Engineering, Petroleum Technology, Corrosion & Metallurgy and Applied Chemistry.