从角节点面推导原子轨道的形状及其分布的对称性

大学化学 Pub Date : 2020-01-01 DOI:10.3866/pku.dxhx201905035

Feng-ling Liu

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引用次数: 0

摘要

原子轨道的形状不仅与方位量子数l有关，还与磁量子数m有关。我们讨论了如何从角节面数目和形状推导出原子轨道的形状，以及当角节面l和|m|已知时，各角节面分布的对称性。根据|m|，还讨论了原子轨道对称的相容性。

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Derivation of the Shape of an Atomic Orbital from the Angular Nodal Planes and the Symmetries of Their Distribution

The shape of an atomic orbital not only depends on the azimuthal quantum number l, but also associates with the magnetic quantum number m. We discussed about how to derive the shape of an atomic orbital from the numbers and shapes of the angular nodal planes, and the symmetries of distribution of all angular nodal planes when l and |m| are known. According to the |m|, the compatibility of the symmetry of an atomic orbitals have also been also discussed.

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来源期刊

大学化学

自引率

0.00%

发文量

5852

期刊介绍： University Chemistry is an educational research academic journal supervised by the Ministry of Education and co-sponsored by Peking University and the Chinese Chemical Society. It was founded in 1986 and changed to a monthly publication in January 2016. Its purpose is to promote and deepen the reform of university chemistry education and serve to improve the level of chemistry teaching in my country. The main columns are: Today's Chemistry, Teaching Research and Reform, Knowledge Introduction, Chemical Experiments, Teacher-Student Chats, Future Chemists, etc. The journal has been included in many databases such as China Journal Network Full-text Database, Wanfang Database, Taiwan Huayi Database, Chinese Science and Technology Journal Database (Full-text Edition), and American Chemical Abstracts.