V. Zavialov, Oleksii Lobok, T. Mysiura, Nataliia Popova, V. Chornyi, Taras Pohorilyi
{"title":"传质动力学模型中未知参数的辨识","authors":"V. Zavialov, Oleksii Lobok, T. Mysiura, Nataliia Popova, V. Chornyi, Taras Pohorilyi","doi":"10.3846/mma.2023.16403","DOIUrl":null,"url":null,"abstract":"An iterative algorithm for identifying unknown parameters of a mathematical model based on the Bayesian approach is proposed, which makes it possible to determine the most probable maximum informative estimates of these parameters. The example of the mathematical model of mass transfer dynamics shows the algorithm for finding the most probable and most informative estimate of the vector of unknown parameters, and also an analysis of the sequence of the corresponding steps is given. The results of computational experiments showed a significant dependence of the results of the calculations on the choice of the initial approximation point and slowing down the rate of convergence of the iterative process (and even its divergence) with an unsuccessful choice of the initial approximation. The validity of the obtained results is provided by analytical conclusions, the results of computational experiments, and statistical modeling. The results of computational experiments make it possible to assert that the proposed algorithm has a sufficiently high convergence for a given degree of accuracy and makes it possible to derive not only estimates of point values of mathematical model parameters based on a posteriori analysis, but also confidence intervals of these estimates. At the same time, it should be noted that the results of calculations depend significantly on the choice of the initial approximation point and the slowing of the convergence rate of the iterative process with an unsuccessful choice of the initial approximation. Analytical studies and results of calculations confirm the effectiveness of the proposed identification algorithm, which makes it possible, with the help of active, purposeful experiments, to build more accurate mathematical models. In accordance with the algorithm, a program was developed in the MatLab mathematics package and computational experiments were performed.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Identification of unknown parameters of the Dynamic Model of mass Transfer\",\"authors\":\"V. Zavialov, Oleksii Lobok, T. Mysiura, Nataliia Popova, V. Chornyi, Taras Pohorilyi\",\"doi\":\"10.3846/mma.2023.16403\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"An iterative algorithm for identifying unknown parameters of a mathematical model based on the Bayesian approach is proposed, which makes it possible to determine the most probable maximum informative estimates of these parameters. The example of the mathematical model of mass transfer dynamics shows the algorithm for finding the most probable and most informative estimate of the vector of unknown parameters, and also an analysis of the sequence of the corresponding steps is given. The results of computational experiments showed a significant dependence of the results of the calculations on the choice of the initial approximation point and slowing down the rate of convergence of the iterative process (and even its divergence) with an unsuccessful choice of the initial approximation. The validity of the obtained results is provided by analytical conclusions, the results of computational experiments, and statistical modeling. The results of computational experiments make it possible to assert that the proposed algorithm has a sufficiently high convergence for a given degree of accuracy and makes it possible to derive not only estimates of point values of mathematical model parameters based on a posteriori analysis, but also confidence intervals of these estimates. At the same time, it should be noted that the results of calculations depend significantly on the choice of the initial approximation point and the slowing of the convergence rate of the iterative process with an unsuccessful choice of the initial approximation. Analytical studies and results of calculations confirm the effectiveness of the proposed identification algorithm, which makes it possible, with the help of active, purposeful experiments, to build more accurate mathematical models. 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Identification of unknown parameters of the Dynamic Model of mass Transfer
An iterative algorithm for identifying unknown parameters of a mathematical model based on the Bayesian approach is proposed, which makes it possible to determine the most probable maximum informative estimates of these parameters. The example of the mathematical model of mass transfer dynamics shows the algorithm for finding the most probable and most informative estimate of the vector of unknown parameters, and also an analysis of the sequence of the corresponding steps is given. The results of computational experiments showed a significant dependence of the results of the calculations on the choice of the initial approximation point and slowing down the rate of convergence of the iterative process (and even its divergence) with an unsuccessful choice of the initial approximation. The validity of the obtained results is provided by analytical conclusions, the results of computational experiments, and statistical modeling. The results of computational experiments make it possible to assert that the proposed algorithm has a sufficiently high convergence for a given degree of accuracy and makes it possible to derive not only estimates of point values of mathematical model parameters based on a posteriori analysis, but also confidence intervals of these estimates. At the same time, it should be noted that the results of calculations depend significantly on the choice of the initial approximation point and the slowing of the convergence rate of the iterative process with an unsuccessful choice of the initial approximation. Analytical studies and results of calculations confirm the effectiveness of the proposed identification algorithm, which makes it possible, with the help of active, purposeful experiments, to build more accurate mathematical models. In accordance with the algorithm, a program was developed in the MatLab mathematics package and computational experiments were performed.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.